Ewing Tamara El-Hayek, Kurig Nils, Yamaki Yoshio Robert, Sun Jiawei, Knowles Timothy R, Gollapudi Asha, Kawamata Yu, Baran Phil S
Department of Chemistry, Scripps Research, 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.
KULR Technology Corp., 4863 Shawline St., Suite B, San Diego, CA, 92111, USA.
Angew Chem Int Ed Engl. 2025 Jan 21;64(4):e202417122. doi: 10.1002/anie.202417122. Epub 2024 Nov 16.
Synthetic organic electrochemistry is recognized as one of the most sustainable forms of redox chemistry that can enable a wide variety of useful transformations. In this study, readily prepared pyrolytic carbon electrodes are explored in several powerful rAP transformations as well as C-C and C-N bond forming reactions. Pyrolytic carbon provides an alternative to classic amorphous carbon-based materials that are either expensive or ill-suited to large-scale flow reactions.
合成有机电化学被认为是氧化还原化学中最具可持续性的形式之一，它能够实现各种各样有用的转化。在本研究中，我们探索了易于制备的热解碳电极在几种强大的自由基加成反应（rAP）以及碳-碳和碳-氮键形成反应中的应用。热解碳为传统的非晶态碳基材料提供了一种替代方案，这些传统材料要么价格昂贵，要么不适合大规模流动反应。
