Peng Wen, Lu Zehang, Liu Enyang, Wu Wenteng, Yu Sirong, Sun Jie
State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, China.
School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China.
J Funct Biomater. 2024 Sep 30;15(10):289. doi: 10.3390/jfb15100289.
As biodegradable materials, zinc (Zn) and zinc-based alloys have attracted wide attention owing to their great potential in biomedical applications. However, the poor strength of pure Zn and binary Zn alloys limits their wide application. In this work, a stir casting method was used to prepare the Zn-1Fe-Sr ( = 0.5, 1, 1.5, 2 wt.%) ternary alloys, and the phase composition, microstructure, tensile properties, hardness, and degradation behavior were studied. The results indicated that the SrZn phase was generated in the Zn matrix when the Sr element was added, and the grain size of Zn-1Fe-Sr alloy decreased with the increase in Sr content. The ultimate tensile strength (UTS) and Brinell hardness increased with the increase in Sr content. The UTS and hardness of Zn-1Fe-2Sr alloy were 141.65 MPa and 87.69 HBW, which were 55.7% and 58.4% higher than those of Zn-1Fe alloy, respectively. As the Sr content increased, the corrosion current density of Zn-1Fe-Sr alloy increased, and the charge transfer resistance decreased significantly. Zn-1Fe-2Sr alloy had a degradation rate of 0.157 mg·cm·d, which was 118.1% higher than the degradation rate of Zn-1Fe alloy. Moreover, the degradation rate of Zn-1Fe-Sr alloy decreased significantly with the increase in immersion time.
作为可生物降解材料,锌(Zn)及其基合金因其在生物医学应用中的巨大潜力而备受关注。然而,纯锌和二元锌合金强度较差,限制了它们的广泛应用。在本研究中,采用搅拌铸造法制备了Zn-1Fe-Sr(=0.5、1、1.5、2 wt.%)三元合金,并对其相组成、微观结构、拉伸性能、硬度和降解行为进行了研究。结果表明,添加Sr元素时,在Zn基体中生成了SrZn相,且Zn-1Fe-Sr合金的晶粒尺寸随Sr含量的增加而减小。抗拉强度(UTS)和布氏硬度随Sr含量的增加而提高。Zn-1Fe-2Sr合金的UTS和硬度分别为141.65 MPa和87.69 HBW,分别比Zn-1Fe合金高55.7%和58.4%。随着Sr含量的增加,Zn-1Fe-Sr合金的腐蚀电流密度增大,电荷转移电阻显著降低。Zn-1Fe-2Sr合金的降解速率为0.157 mg·cm·d,比Zn-1Fe合金的降解速率高118.1%。此外,Zn-1Fe-Sr合金的降解速率随浸泡时间的增加而显著降低。