Jordá-Reolid María, Martínez-García Asunción, Ibáñez-García Ana, León-Cabezas Miguel Ángel, Galvañ-Gisbert Josefa
Innovative Materials and Manufacturing Area, Technological Institute for Children's Products and Leisure, 03440 Ibi, Spain.
Polymers (Basel). 2024 Oct 17;16(20):2916. doi: 10.3390/polym16202916.
The influence of bagasse fibres from beer manufacturing in mechanical, thermal, and rheological properties of three polymers (BioPE, PLA, and PP) has been studied in order to develop new environmentally friendly biocomposites for injection moulding applications. Totals of 10 wt%, 20 wt%, and 30 wt% of bagasse fibre (BSG) were added to the polymers by extrusion compounding, adding specific compatibilising additives, and injected samples were mechanically characterised by tensile, Charpy impact, and hardness tests. In addition, the fractures obtained after the impact test were observed using scanning electron microscopy (SEM) to assess the compatibility matrix filler. Characterisation of the thermal properties is also carried out by using differential scanning calorimetry (DSC) and thermogravimetry (TGA). Additionally, melt flow index of the biocomposites is also studied. An increase in the rigidity of the BioPE and PP composites was produced with the increase in BSG content, dealing with a decrease in maximum strain and impact resistance; whereas, in the filled BGS PLA biocomposites, Young's modulus was lower than that of the PLA material, improving the ductility of the PLA-BGS formulations. Compatibilisation effect was, therefore, different in the nine developed formulations, and the BGS content also influenced their thermal, mechanical, and rheological behaviours.
为开发用于注塑应用的新型环保生物复合材料,研究了啤酒生产中的甘蔗渣纤维对三种聚合物(生物聚乙烯、聚乳酸和聚丙烯)的机械、热学和流变学性能的影响。通过挤出共混将10重量%、20重量%和30重量%的甘蔗渣纤维(BSG)添加到聚合物中,添加特定的相容添加剂,并通过拉伸、夏比冲击和硬度测试对注塑样品进行机械表征。此外,使用扫描电子显微镜(SEM)观察冲击试验后获得的断裂情况,以评估基体与填料的相容性。还通过差示扫描量热法(DSC)和热重分析法(TGA)对热性能进行表征。此外,还研究了生物复合材料的熔体流动指数。随着BSG含量的增加,生物聚乙烯和聚丙烯复合材料的刚性增加,同时最大应变和抗冲击性降低;而在填充BSG的聚乳酸生物复合材料中,杨氏模量低于聚乳酸材料,提高了聚乳酸 - BGS配方的延展性。因此,在九种开发的配方中,相容化效果不同,BSG含量也影响它们的热、机械和流变行为。