Zhang Shutao, Zhang Jun, Goh Wei Peng, Liu Yan, Tjiptoharsono Febiana, Lee Henry Yit Loong, Jiang Changyun, Ding Jun, Yang Joel K W, Dong Zhaogang
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, #08-03 Innovis, 138634, Singapore, Singapore.
Singapore University of Technology and Design, 8 Somapah Road, 487372, Singapore, Singapore.
Nanophotonics. 2023 Jan 17;12(8):1387-1395. doi: 10.1515/nanoph-2022-0646. eCollection 2023 Apr.
Electrical switching of nanophotonic structural color elements is a promising approach towards addressable color switching pixels for next generation reflective displays. However, electrical switching between the primary colors to colorless near-white state remains a challenge. Here, we present a reversible electrical switching approach, relying on the electrocoagulation of Ag nanoparticles between silicon nanostructures that support Mie resonances. The electrodeposited Ag nanoparticles enable the excitation of the hybrid plasmon-Mie resonance as supported on Ag-silicon nanostructures, resulting in a large spectral transformation. Importantly, this process is reversible. This device design outperforms other designs in terms of electrotonic color control since it is highly stable and reliable for use in high-resolution reflective displays, such as colored electronic papers and smart display glass, where the combination is scalable to other nanostructure designs and electrolytic solutions.
纳米光子结构色元件的电开关是实现下一代反射式显示器中可寻址颜色切换像素的一种很有前景的方法。然而,从原色到无色近白色状态的电开关仍然是一个挑战。在此,我们提出一种可逆电开关方法,该方法依赖于支持米氏共振的硅纳米结构之间银纳米颗粒的电凝聚。电沉积的银纳米颗粒能够激发银 - 硅纳米结构上支持的混合等离子体 - 米氏共振,从而导致大的光谱转变。重要的是,这个过程是可逆的。这种器件设计在电致变色控制方面优于其他设计,因为它高度稳定且可靠,可用于高分辨率反射式显示器,如彩色电子纸和智能显示玻璃,并且这种组合可扩展到其他纳米结构设计和电解液。