Dong Zhaogang, Jin Lei, Rezaei Soroosh Daqiqeh, Wang Hao, Chen Yang, Tjiptoharsono Febiana, Ho Jinfa, Gorelik Sergey, Ng Ray Jia Hong, Ruan Qifeng, Qiu Cheng-Wei, Yang Joel K W
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, #08-03 Innovis, Singapore 138634, Singapore.
Department of Materials Science and Engineering, National University of Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
Sci Adv. 2022 Feb 25;8(8):eabm4512. doi: 10.1126/sciadv.abm4512. Epub 2022 Feb 23.
While structural colors are ubiquitous in nature, saturated reds are mysteriously absent. This long-standing problem of achieving Schrödinger's red demands sharp transitions from "stopband" to a high-reflectance "passband" with total suppression of higher-order resonances at blue/green wavelengths. Current approaches based on nanoantennas are insufficient to satisfy all conditions simultaneously. Here, we designed Si nanoantennas to support two partially overlapping quasi-bound-states-in-the-continuum modes with a gradient descent algorithm to achieve sharp spectral edges at red wavelengths. Meanwhile, high-order modes at blue/green wavelengths are suppressed via engineering the substrate-induced diffraction channels and the absorption of amorphous Si. This design produces possibly the most saturated and brightest reds with ~80% reflectance, exceeding the red vertex in sRGB and even the cadmium red pigment. Its nature of being sensitive to polarization and illumination angle could be potentially used for information encryption, and this proposed paradigm could be generalized to other Schrödinger's color pixels.
虽然结构色在自然界中无处不在,但饱和红色却神秘地缺失。实现薛定谔红色这一长期存在的问题要求从“阻带”到高反射“通带”有急剧的转变,并完全抑制蓝/绿波长处的高阶共振。目前基于纳米天线的方法不足以同时满足所有条件。在这里,我们设计了硅纳米天线,通过梯度下降算法支持两种部分重叠的连续态准束缚态模式,以在红色波长处实现尖锐的光谱边缘。同时,通过设计衬底诱导的衍射通道和非晶硅的吸收来抑制蓝/绿波长处的高阶模式。这种设计产生了可能是最饱和、最亮的红色,反射率约为80%,超过了sRGB中的红色顶点,甚至超过了镉红颜料。其对偏振和照明角度敏感的特性可能潜在地用于信息加密,并且这种提出的范式可以推广到其他薛定谔颜色像素。