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在傅里叶变换红外光谱检测的氩/氢/氮气体混合物中脉冲空心阴极放电过程中氨的生成。

Generation of Ammonia in a Pulsed Hollow Cathode Discharge Operated in an Ar/H/N Gas Mixture Detected by Fourier Transform Infrared.

作者信息

Hippler Rainer, Cada Martin, Knizek Antonin, Ferus Martin, Hubicka Zdenek

机构信息

Institute of Physics, Czech Academy of Sciences, Na Slovance 2, 18200 Prague, Czech Republic.

Institut für Physik, Universität Greifswald, Felix-Hausdorff-Strasse 6, 17489 Greifswald, Germany.

出版信息

ACS Sustain Chem Eng. 2024 Nov 15;12(48):17443-17449. doi: 10.1021/acssuschemeng.4c08054. eCollection 2024 Dec 2.

DOI:10.1021/acssuschemeng.4c08054
PMID:39641128
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11615948/
Abstract

A hollow cathode discharge with a copper nickel cathode (Cu50Ni50) was operated in an Ar/H/N gas mixture. Optical emission spectroscopy revealed the formation of NH radicals, which serve as precursors for NH formation. Ion mass spectrometry showed the formation of NH and NH ions indicating NH formation. Gas samples taken at the exhaust of the vacuum system were analyzed by Fourier transform infrared spectroscopy. Clear evidence for NH formation was obtained from these measurements.

摘要

一个带有铜镍阴极（Cu50Ni50）的空心阴极放电装置在氩/氢/氮气体混合物中运行。光发射光谱显示形成了NH自由基，其作为NH形成的前驱体。离子质谱表明形成了NH⁺和NH₂⁺离子，这表明有NH形成。通过傅里叶变换红外光谱对在真空系统排气口采集的气体样品进行了分析。从这些测量中获得了NH形成的确凿证据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/4a3cd6096e99/sc4c08054_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/6ad90c761521/sc4c08054_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/880da920e971/sc4c08054_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/e354922fefb8/sc4c08054_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/aca82cc4f33f/sc4c08054_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/ece5a53a7d72/sc4c08054_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/4a3cd6096e99/sc4c08054_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/6ad90c761521/sc4c08054_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/880da920e971/sc4c08054_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/e354922fefb8/sc4c08054_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/aca82cc4f33f/sc4c08054_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/ece5a53a7d72/sc4c08054_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff84/11615948/4a3cd6096e99/sc4c08054_0006.jpg

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本文引用的文献

1
Kinetic Modeling Analysis of Ar Addition to Atmospheric Pressure N-H Plasma for Plasma-Assisted Catalytic Synthesis of NH.用于等离子体辅助催化合成氨的氩气添加到大气压氮-氢等离子体中的动力学建模分析
J Phys Chem A. 2024 Mar 13. doi: 10.1021/acs.jpca.3c06841.
2
A stable atmospheric-pressure plasma for extreme-temperature synthesis.一种用于极端温度合成的稳定常压等离子体。
Nature. 2023 Nov;623(7989):964-971. doi: 10.1038/s41586-023-06694-1. Epub 2023 Nov 29.
3
Multiple reaction pathway on alkaline earth imide supported catalysts for efficient ammonia synthesis.
用于高效合成氨的碱土酰亚胺负载型催化剂上的多反应途径
Nat Commun. 2023 Oct 11;14(1):6373. doi: 10.1038/s41467-023-42050-7.
4
Mechanochemistry for ammonia synthesis under mild conditions.温和条件下用于氨合成的机械化学
Nat Nanotechnol. 2021 Mar;16(3):325-330. doi: 10.1038/s41565-020-00809-9. Epub 2020 Dec 14.
5
Unconventional Catalytic Approaches to Ammonia Synthesis.非常规氨合成催化方法。
Annu Rev Chem Biomol Eng. 2020 Jun 7;11:503-521. doi: 10.1146/annurev-chembioeng-092319-080240. Epub 2020 Mar 10.
6
Plasma-Enhanced Catalytic Synthesis of Ammonia over a Ni/AlO Catalyst at Near-Room Temperature: Insights into the Importance of the Catalyst Surface on the Reaction Mechanism.近室温下在Ni/AlO催化剂上通过等离子体增强催化合成氨：深入了解催化剂表面对反应机理的重要性。
ACS Catal. 2019 Dec 6;9(12):10780-10793. doi: 10.1021/acscatal.9b02538. Epub 2019 Oct 18.
7
Beyond fossil fuel-driven nitrogen transformations.超越化石燃料驱动的氮转化。
Science. 2018 May 25;360(6391). doi: 10.1126/science.aar6611.
8
Proton transfer chains in cold plasmas of H2 with small amounts of N2. The prevalence of NH4(+).质子转移链在含少量 N2 的 H2 冷等离子体中。NH4(+) 的普遍存在。
Phys Chem Chem Phys. 2013 Feb 7;15(5):1699-706. doi: 10.1039/c2cp43438e.
9
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Phys Chem Chem Phys. 2011 Nov 21;13(43):19561-72. doi: 10.1039/c1cp22284h. Epub 2011 Oct 10.
10
Unimolecular and bimolecular calculations for HN2.
J Phys Chem A. 2005 Mar 17;109(10):2356-63. doi: 10.1021/jp045102g.