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石墨烯增强铝基金属基复合材料的场发射性能

Field emission performance of graphene-incorporated aluminum-based metal matrix composite.

作者信息

Pradhan Sunil Kumar, K Pandiyarajan, Patil Shubham, Chavan Padmakar G, Monteiro Lobato Raphael Longuinhos, Ribeiro-Soares Jenaina, Late Dattatray J

机构信息

School of Electronics Engineering, Vellore Institute of Technology Chennai 600127 India

School of Advanced Sciences, Vellore Institute of Technology Chennai 600127 India.

出版信息

Nanoscale Adv. 2024 Nov 25;7(2):614-620. doi: 10.1039/d4na00646a. eCollection 2025 Jan 14.

Abstract

The 'close proximity' configuration was used for field emission analysis of graphene-incorporated aluminum (Al) composites. The turn-on field was found to be 2 V μm for the AlGr1 (1% graphene (by weight) inside the Al matrix) composite compared to 4.75 V μm for the pristine aluminum sample. As the potential was increased, the current due to emission expeditiously increased in an electric field of 4 V μm, with 1 mA cm current density due to emission for the AlGr1 composite, compared to that of 1.08 μA cm for Al. The turn-on value was visually perceived to be superior for the AlGr1 composite as compared to the value for Al. Also, a quite stable emission current was recorded for the AlGr1 composite as compared to Al. Furthermore, the composites maintained approximately 98.7% of the density of pure aluminum following the sintering process. The structural wholeness and the nonexistent porous quality of the sintered specimens was confirmed X-ray micro-computed tomography (micro-CT). The thermal amalgamation of the AlGr composite materials at 640 °C was found to be adequate, and produced composites with the desired strength. These evaluations indicate that AlGr composites can be excellently applied as cathodes and for the prevention of crumpling of electrical line cables.

摘要

“紧密接近”配置用于含石墨烯铝(Al)复合材料的场发射分析。对于AlGr1(Al基体中含1%(重量)石墨烯)复合材料,开启场强为2 V/μm,而原始铝样品的开启场强为4.75 V/μm。随着电势增加,在4 V/μm的电场中,由于发射导致的电流迅速增加,AlGr1复合材料的发射电流密度为1 mA/cm²,而Al的发射电流密度为1.08 μA/cm²。从视觉上看,AlGr1复合材料的开启值优于Al的开启值。此外,与Al相比,AlGr1复合材料记录到的发射电流相当稳定。此外,烧结后复合材料的密度约保持纯铝密度的98.7%。通过X射线微计算机断层扫描(micro-CT)确认了烧结试样的结构完整性和不存在多孔性。发现AlGr复合材料在640℃的热融合是充分的,并生产出具有所需强度的复合材料。这些评估表明,AlGr复合材料可出色地用作阴极并用于防止电线电缆起皱。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c699/11731223/1c868fe9bf0d/d4na00646a-f1.jpg

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