Ali Muhammad Faizan, Ochiai Bungo
Department of Applied Chemistry, Chemical Engineering, and Biochemical Engineering, Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa 992-8510, Yamagata, Japan.
Polymers (Basel). 2024 Nov 25;16(23):3275. doi: 10.3390/polym16233275.
Graft copolymers have gained significant importance in various fields due to their tunable functionality and well-defined architecture. However, there are still limitations due to the compatibility of monomers and functional groups depending on the polymerization mode. Click chemistry has solved this problem through its ability to easily and quantitatively link a wide range of polymers and functional groups. The combination of click chemistry, including copper-catalyzed azide-alkyne cycloaddition (CuAAC), thiol-ene, and thiol-yne reactions, with various polymerization techniques offers a promising solution for the robust and efficient preparation of graft copolymers with the desired architecture and functionality. In this review, we present successful applications of click chemistry in the production of well-defined graft copolymers with diverse functionalities such as for electronics, energy devices, biomedical applications, and nanotechnology.
接枝共聚物因其可调谐的功能和明确的结构在各个领域都变得极为重要。然而，由于取决于聚合模式的单体和官能团的相容性，仍然存在局限性。点击化学通过其能够轻松且定量地连接多种聚合物和官能团的能力解决了这个问题。包括铜催化的叠氮化物-炔烃环加成反应（CuAAC）、硫醇-烯反应和硫醇-炔反应在内的点击化学与各种聚合技术的结合，为稳健且高效地制备具有所需结构和功能的接枝共聚物提供了一个有前景的解决方案。在这篇综述中，我们展示了点击化学在制备具有多种功能（如用于电子、能源器件、生物医学应用和纳米技术）的明确接枝共聚物方面的成功应用。
