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使用VAUS化学处理提高硅藻生物硅的回收率。

Improving Recovery of Diatoms Bio-Silica Using Chemical Treatment with VAUS.

作者信息

Suh Se Ryung, Lee Joo Hun, Go Gyung Min, Lee Jaeyoung, Kong Hyunjoon, Park Eun-Jin

机构信息

Department of Prosthodontics, Graduate School of Clinical Dentistry, Ewha Womans University, Seoul 07985, Republic of Korea.

Department of Chemical and Biomolecular Engineering, University of Illinois Urbana-Champaign, Urbana, IL 61801, USA.

出版信息

Materials (Basel). 2024 Nov 23;17(23):5742. doi: 10.3390/ma17235742.

Abstract

High-temperature baking is a typical method to remove organic matter from diatoms, but it is not suitable for bio-silica because of the high crystallinity. This study provides a method using the VAUS to remove organic matter from diatoms more quickly and biocompatibly. The optimal frequency for organic matter removal was investigated for domestically produced . The removal efficiency of TOC/TN was calculated and analyzed. The C and Si elements were analyzed in EDS, and organic matter removal was analyzed by XRD. TOC RE% at a frequency of 35 kHz exhibited the highest value, indicating a statistically significant difference. XRD analysis demonstrated that the organic matter was nearly entirely removed using NaOCl compared to high-temperature-baked . In the EDS analysis, there were significant differences in the C and Si elements with respect to frequency. This is very similar to the values from the positive control group, high-temperature-baked . Ultrasonic treatment and frequency adjustments were found to significantly impact the chemical removal of organic matter from . Although vacuum application was initially considered, it did not demonstrate a statistically significant effect according to TOC analysis.

摘要

高温烘焙是从硅藻中去除有机物的一种典型方法,但由于结晶度高,它不适用于生物二氧化硅。本研究提供了一种使用VAUS更快且生物相容性更好地从硅藻中去除有机物的方法。研究了国产硅藻去除有机物的最佳频率。计算并分析了TOC/TN的去除效率。在能谱仪(EDS)中分析了碳(C)和硅(Si)元素,并通过X射线衍射(XRD)分析了有机物的去除情况。35kHz频率下的总有机碳去除率(TOC RE%)显示出最高值,表明存在统计学上的显著差异。XRD分析表明,与高温烘焙的硅藻相比,使用次氯酸钠(NaOCl)几乎完全去除了有机物。在EDS分析中,碳和硅元素在频率方面存在显著差异。这与阳性对照组(高温烘焙的硅藻)的值非常相似。发现超声处理和频率调整对从硅藻中化学去除有机物有显著影响。尽管最初考虑了施加真空,但根据TOC分析,它并未显示出统计学上的显著效果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22cf/11642400/1d4770532ef9/materials-17-05742-g001.jpg

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