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关于用于医疗应用的沉积在2级钛上的多层硅烷-羟基磷灰石涂层的防腐效果的初步研究

Preliminary Aspects Regarding the Anticorrosive Effect of Multi-Layered Silane-Hydroxyapatite Coatings Deposited on Titanium Grade 2 for Medical Applications.

作者信息

Dudek Agata, Kierat Oliwia

机构信息

Department of Material Engineering, Faculty of Production Engineering and Materials Technology, Czestochowa University of Technology, Aleja Armii Krajowej 19, 42-200 Czestochowa, Poland.

出版信息

Materials (Basel). 2024 Dec 7;17(23):6001. doi: 10.3390/ma17236001.

DOI:10.3390/ma17236001
PMID:39685437
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11643174/
Abstract

This paper presents a method for producing VTMS/HAp/VTMS/VTMS multilayer coatings on a Grade 2 titanium substrate and characterizes their structure and functional properties. Two solutions were used to produce the coatings: one based on vinyltrimethoxysilane (VTMS) and the other on hydroxyapatite (HAp) powder. The coatings were applied using immersion using the sol-gel method. Microstructural tests of the multilayer coatings were performed, their chemical composition was determined, and the structure was characterized using Fourier Transform Infrared Spectroscopy (FTIR). A detailed analysis of the geometric structure of the coatings was carried out both before and after corrosion tests. The geometric structure of the multilayer coatings was analyzed using a light microscope and an atomic force microscope (AFM). The thickness of the coatings was determined using a Testan DT-10 AN 120 157 m, and the adhesion of the coatings to the substrate was analyzed using Scotch™ tape. The corrosion resistance of the coatings in simulated body fluid was tested to evaluate their suitability for implantology. As demonstrated by the research presented in this paper, the sol-gel process can successfully produce silane coatings by adding hydroxyapatite powder. The new materials proposed in this study can effectively protect metal materials used in medicine against corrosion.

摘要

本文介绍了一种在2级钛基底上制备VTMS/HAp/VTMS/VTMS多层涂层的方法，并对其结构和功能特性进行了表征。使用两种溶液来制备涂层：一种基于乙烯基三甲氧基硅烷（VTMS），另一种基于羟基磷灰石（HAp）粉末。采用溶胶-凝胶法通过浸泡来施加涂层。对多层涂层进行了微观结构测试，确定了其化学成分，并使用傅里叶变换红外光谱（FTIR）对结构进行了表征。在腐蚀测试前后都对涂层的几何结构进行了详细分析。使用光学显微镜和原子力显微镜（AFM）分析了多层涂层的几何结构。使用Testan DT-10 AN 120 157 m测定涂层的厚度，并使用思高™胶带分析涂层与基底的附着力。测试了涂层在模拟体液中的耐腐蚀性，以评估其在植入学中的适用性。如本文所呈现的研究所表明的，溶胶-凝胶工艺通过添加羟基磷灰石粉末能够成功制备硅烷涂层。本研究中提出的新材料能够有效保护医学中使用的金属材料免受腐蚀。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/682563a96941/materials-17-06001-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/cb1b4954e0ab/materials-17-06001-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/f19e99ba2684/materials-17-06001-g009.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/682563a96941/materials-17-06001-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/cb1b4954e0ab/materials-17-06001-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/c5066e349221/materials-17-06001-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/913c436c0669/materials-17-06001-g003.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/1bc12e2e6905/materials-17-06001-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/d7a2e1668291/materials-17-06001-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/7398963a8896/materials-17-06001-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/f19e99ba2684/materials-17-06001-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/bbbf8a38ba29/materials-17-06001-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40bf/11643174/682563a96941/materials-17-06001-g011.jpg

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2
Surface modification techniques of titanium and titanium alloys for biomedical orthopaedics applications: A review.用于生物医学矫形应用的钛及钛合金的表面改性技术：综述。
Colloids Surf B Biointerfaces. 2023 Jul;227:113339. doi: 10.1016/j.colsurfb.2023.113339. Epub 2023 May 9.
3
Synthesis of superhydrophobic coatings based on silica nanostructure modified with organosilane compounds by sol-gel method for glass surfaces.
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Sci Rep. 2023 Jan 11;13(1):548. doi: 10.1038/s41598-023-27811-0.
4
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5
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6
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Dent Clin North Am. 2019 Jul;63(3):447-460. doi: 10.1016/j.cden.2019.02.010. Epub 2019 Apr 12.
7
Surface engineering of titanium-based implants using electrospraying and dip coating methods.采用静电喷涂和浸涂法对钛基植入物进行表面工程处理。
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8
Review of titanium surface modification techniques and coatings for antibacterial applications.钛表面改性技术及抗菌涂层的研究进展。
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10
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