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检测蜂蜜掺假:采用超滤-气相色谱联用机器学习的先进方法

Detecting Honey Adulteration: Advanced Approach Using UF-GC Coupled with Machine Learning.

作者信息

Punta-Sánchez Irene, Dymerski Tomasz, Calle José Luis P, Ruiz-Rodríguez Ana, Ferreiro-González Marta, Palma Miguel

机构信息

Department of Analytical Chemistry, Faculty of Sciences, University of Cadiz, Agrifood Campus of International Excellence (ceiA3), IVAGRO, 11510 Puerto Real, Spain.

Department of Analytical Chemistry, Faculty of Chemistry, Gdańsk University of Technology, 11/12 G, Narutowicza Str., 80-233 Gdansk, Poland.

出版信息

Sensors (Basel). 2024 Nov 23;24(23):7481. doi: 10.3390/s24237481.

DOI:10.3390/s24237481
PMID:39686019
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11644204/
Abstract

This article introduces a novel approach to detecting honey adulteration by combining ultra-fast gas chromatography (UF-GC) with advanced machine learning techniques. Machine learning models, particularly support vector regression (SVR) and least absolute shrinkage and selection operator (LASSO), were applied to predict adulteration in orange blossom (OB) and sunflower (SF) honeys. The SVR model achieved R values above 0.90 for combined honey types. Treating OB and SF honeys separately resulted in a significant accuracy improvement, with R values exceeding 0.99. LASSO proved especially effective when honey types were treated individually. The integration of UF-GC with machine learning not only provides a reliable method for detecting honey adulteration, but also sets a precedent for future research in the application of this technique to other food products, potentially enhancing food authenticity across the industry.

摘要

本文介绍了一种将超快速气相色谱法(UF-GC)与先进的机器学习技术相结合来检测蜂蜜掺假的新方法。应用机器学习模型,特别是支持向量回归(SVR)和最小绝对收缩和选择算子(LASSO)来预测橙花(OB)蜂蜜和向日葵(SF)蜂蜜中的掺假情况。对于混合蜂蜜类型,SVR模型的R值高于0.90。分别处理OB蜂蜜和SF蜂蜜可显著提高准确率,R值超过0.99。当单独处理蜂蜜类型时,LASSO被证明特别有效。UF-GC与机器学习的结合不仅为检测蜂蜜掺假提供了一种可靠的方法,也为该技术在其他食品中的应用的未来研究树立了先例,有可能提高整个行业食品的真实性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d742/11644204/54260e0af55f/sensors-24-07481-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d742/11644204/180bbe2cf7f1/sensors-24-07481-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d742/11644204/54260e0af55f/sensors-24-07481-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d742/11644204/180bbe2cf7f1/sensors-24-07481-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d742/11644204/54260e0af55f/sensors-24-07481-g002.jpg

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本文引用的文献

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Ultraviolet-visible spectroscopy combined with machine learning as a rapid detection method to the predict adulteration of honey.紫外可见光谱法结合机器学习作为一种快速检测方法来预测蜂蜜掺假情况。
Heliyon. 2023 Oct 13;9(10):e20973. doi: 10.1016/j.heliyon.2023.e20973. eCollection 2023 Oct.
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A comprehensive review of the current trends and recent advancements on the authenticity of honey.对蜂蜜真实性的当前趋势和最新进展的全面综述。
Food Chem X. 2023 Aug 28;19:100850. doi: 10.1016/j.fochx.2023.100850. eCollection 2023 Oct 30.
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Rapid and Automated Method for Detecting and Quantifying Adulterations in High-Quality Honey Using Vis-NIRs in Combination with Machine Learning.
使用可见-近红外光谱结合机器学习快速自动检测和定量优质蜂蜜掺假物的方法
Foods. 2023 Jun 26;12(13):2491. doi: 10.3390/foods12132491.
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Determination of Possible Adulteration and Quality Assessment in Commercial Honey.商业蜂蜜中可能存在的掺假物测定及质量评估
Foods. 2023 Jan 24;12(3):523. doi: 10.3390/foods12030523.
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Comprehensive examination and comparison of machine learning techniques for the quantitative determination of adulterants in honey using Fourier infrared spectroscopy with attenuated total reflectance accessory.采用傅里叶变换衰减全反射红外光谱法结合化学计量学技术定量检测蜂蜜中掺杂物的综合考察与比较。
Spectrochim Acta A Mol Biomol Spectrosc. 2022 Aug 5;276:121186. doi: 10.1016/j.saa.2022.121186. Epub 2022 Mar 29.
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Identification and quantification of adulterated honey by Raman spectroscopy combined with convolutional neural network and chemometrics.拉曼光谱结合卷积神经网络和化学计量学鉴定和量化掺假蜂蜜。
Spectrochim Acta A Mol Biomol Spectrosc. 2022 Jun 5;274:121133. doi: 10.1016/j.saa.2022.121133. Epub 2022 Mar 10.
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The Use of SPME-GC-MS IR and Raman Techniques for Botanical and Geographical Authentication and Detection of Adulteration of Honey.固相微萃取-气相色谱-质谱联用红外和拉曼技术在蜂蜜植物来源及产地鉴别与掺假检测中的应用
Foods. 2021 Jul 20;10(7):1671. doi: 10.3390/foods10071671.
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