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纳米和微纤维口罩过滤器的灭菌及过滤性能——用于竞争型可持续替代方案的静电纺丝及电荷恢复

Sterilization and Filter Performance of Nano- and Microfibrous Facemask Filters - Electrospinning and Restoration of Charges for Competitive Sustainable Alternatives.

作者信息

Herwig Gordon, Batt Till, Clement Pietro, Wick Peter, Rossi René M

机构信息

Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Biomimetic Membranes and Textiles, St. Gallen, 9014, Switzerland.

Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Particles-Biology Interactions, St. Gallen, 9014, Switzerland.

出版信息

Macromol Rapid Commun. 2025 Jul;46(13):e2400867. doi: 10.1002/marc.202400867. Epub 2024 Dec 27.

DOI:10.1002/marc.202400867
PMID:39731334
Abstract

Facemask materials have been under constant development to optimize filtration performance, wear comfort, and general resilience to chemical and mechanical stress. While single-use polypropylene meltblown membranes are the established go-to material for high-performing mask filters, they are neither sustainable nor particularly resistant to sterilization methods. Herein an in-depth analysis is provided of the sterilization efficiency, filtration efficiency, and breathing resistance of selected aerosol filters commonly implemented in facemasks, with a particular focus on the benefits of nanofibrous filters. After establishing a general overview over face mask filters and machine washing parameters required for successful decontamination, respective changes in filter performance and structure are presented. Sustainably manufactured, highly efficient, but also more fragile electrospun membranes not only offer competitive performance as well as a more environment-friendly production and degradation process, but also support a subsequent sterilization and recharging approach via alcohol exposition and drying in an electric field. It is further elaborated on the prospective sustainability of each material to offer a clear outlook on electrospun membranes as the most promising filter membranes of the future.

摘要

口罩材料一直在不断发展,以优化过滤性能、佩戴舒适度以及对化学和机械应力的总体耐受性。虽然一次性聚丙烯熔喷膜是高性能口罩过滤器的既定首选材料,但它们既不具有可持续性,对灭菌方法的耐受性也不强。本文对口罩中常用的选定气溶胶过滤器的灭菌效率、过滤效率和呼吸阻力进行了深入分析,特别关注了纳米纤维过滤器的优势。在对口罩过滤器和成功去污所需的机洗参数进行总体概述之后,介绍了过滤器性能和结构的相应变化。可持续制造的、高效但也更脆弱的电纺膜不仅具有具有竞争力的性能以及更环保的生产和降解过程,还支持通过酒精暴露和电场干燥进行后续灭菌和再充电的方法。本文进一步阐述了每种材料的潜在可持续性,以清晰展望电纺膜作为未来最有前景的过滤膜。

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