Meyn Jan-Peter
Department Physik, Friedrich-Alexander-Universität Erlangen-Nürnberg, Staudtstraße 7, 91058 Erlangen, Germany.
Entropy (Basel). 2024 Nov 21;26(12):1002. doi: 10.3390/e26121002.
Entropy and energy had not yet been introduced to physics by the time Carnot wrote his seminal Réflexions. Scholars continue to discuss what he really had in mind and what misconceptions he might have had. Actually, his work can be read as a correct introduction to the physics of heat engines when the term calorique is replaced by entropy and entropy is used as the other fundamental thermal quantity besides temperature. Carnot's concepts of falling entropy as an analogy to the waterfall, and the separation of real thermal processes into reversible and irreversible processes are adopted. Some details of Carnot's treatise are ignored, but the principal ideas are quoted and assumed without modification. With only two thermal quantities, temperature and entropy, modern heat engines can be explained in detail. Only after the principal function of heat engines is developed is energy introduced as physical quantity in order to compare thermal engines with mechanical and electrical engines and, specifically, to calculate efficiency.
在卡诺撰写其具有开创性的《反思》时,熵和能量尚未被引入物理学。学者们仍在讨论他真正的想法以及他可能存在的误解。实际上,当用熵取代“热质”一词,并将熵用作除温度之外的另一个基本热学量时,他的著作可以被视为对热机物理学的正确介绍。卡诺将熵的降低类比为瀑布,以及将实际热过程分为可逆和不可逆过程的概念被采用。卡诺论文的一些细节被忽略了,但主要思想被引用且未作修改。仅用温度和熵这两个热学量,就可以详细解释现代热机。只有在热机的主要功能阐述之后,能量才作为物理量被引入,以便将热机与机械和电气发动机进行比较,特别是为了计算效率。