Kim Taeho, Yoon Cheolhee, Jung Seungho
Department of Environmental and Safety Engineering, Ajou University, Suwon 16499, Republic of Korea.
Int J Environ Res Public Health. 2024 Dec 10;21(12):1649. doi: 10.3390/ijerph21121649.
The demand for the use of secondary batteries is increasing rapidly worldwide in order to solve global warming and achieve carbon neutrality. Major minerals used to produce cathode materials, which are key raw materials for secondary batteries, are treated as conflict minerals due to their limited reserves, and accordingly, research on the battery recycling industry is urgent for the sustainable secondary battery industry. There is a significant risk of accidents because there is a lack of prior research data on the battery recycling process and various chemicals are used in the entire recycling process. Therefore, for the safety management of related industries, it is necessary to clearly grasp the battery recycling process and to estimate the risk accordingly. In this study, the process was generalized using the information on the battery recycling process suggested in the preceding literature. And to estimate the relative risk of each battery recycling process, the RAC (Risk Assessment Code) matrix described in the US Department of Defense's "MIL-STD-882E" was used. Severity was derived by using "NFPA 704", and probability was derived by combining generalized event analysis for each process and the WEEE (Waste Electrical and Electronic Equipment) report. The results confirmed that the process using HSO had the highest risk when extracting Li during the leaching process, and that dismantling and heat treatment had the lowest risk. Using the probability factor for each process calculated through the research, it is expected to be used in future battery recycling process research as basic data for quantitative risk assessment of the battery recycling process.
为了解决全球变暖问题并实现碳中和,全球对二次电池的使用需求正在迅速增长。用于生产二次电池关键原材料正极材料的主要矿物,因其储量有限而被视为冲突矿物,因此,对于可持续的二次电池产业而言,电池回收行业的研究迫在眉睫。由于缺乏关于电池回收过程的前期研究数据,且整个回收过程中使用了各种化学物质,存在重大事故风险。因此,为了相关行业的安全管理,有必要清楚地掌握电池回收过程并据此评估风险。在本研究中,利用先前文献中提出的电池回收过程信息对该过程进行了归纳。为了评估每个电池回收过程的相对风险,使用了美国国防部《MIL-STD-882E》中描述的RAC(风险评估代码)矩阵。严重程度通过使用“NFPA 704”得出,概率通过结合每个过程的归纳事件分析和WEEE(废弃电气和电子设备)报告得出。结果证实,在浸出过程中提取锂时,使用HSO的过程风险最高,而拆解和热处理风险最低。利用通过该研究计算出的每个过程的概率因子,有望作为电池回收过程定量风险评估的基础数据,用于未来的电池回收过程研究。