钼催化的炔烃的（）-选择性反马氏硅氢化反应

Ye Feihua, Huang Zhaoyang, Li Jiahao, Wang Qiumin, Wu Lihuan, Li Xiang

School of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China.

Molecules. 2024 Dec 17;29(24):5952. doi: 10.3390/molecules29245952.

Herein, we report the first example of molybdenum-catalyzed ()-Selective anti-Markovnikov hydrosilylation of alkynes. The reaction operates effectively with the utilization of minute amounts of the inexpensive, bench-stable pre-catalyst and ligand under mild conditions. Moreover, this molybdenum-catalyzed hydrosilylation process features the advantages of simple operation, excellent selectivity, and broad functional groups tolerance.

在此，我们报道了钼催化炔烃的（）-选择性反马氏硅氢化反应的首例。该反应在温和条件下，利用微量廉价、易于保存的预催化剂和配体即可有效进行。此外，这种钼催化的硅氢化反应具有操作简单、选择性优异以及对多种官能团耐受性良好的优点。