Segundo-Osorio Miriam, Gómora-Figueroa A Paulina, Solis-Ibarra Diego
Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México Circuito Exterior s/n, CU, Coyoacán 04510 Ciudad de México Mexico
División de Ingeniería en Ciencias de la Tierra, Facultad de Ingeniería, Universidad Nacional Autónoma de México, Ciudad Universitaria Circuito Exterior 04510 Ciudad de México Mexico.
Chem Sci. 2025 Jan 6;16(3):999-1001. doi: 10.1039/d4sc90244k. eCollection 2025 Jan 15.
Hybrid organic-inorganic perovskites (HOIPs) are widely studied for their potential in optoelectronic devices due to their unique semiconductor features. Porous HOIPs are extremely rare, with (APOSS)[CuCl] being one of the very few examples, featuring 12 Å pores within its lattice. Reed and coworkers (C. W. Dalton, P. M. Gannon, W. Kaminsky and D. A. Reed, , 2025, DOI: https://doi.org/10.1039/D4SC04378B) have recently shed light on the structure of this interesting material and demonstrated that these pores can incorporate large electroactive molecules such as ferrocene (Fc) and tetracyanoethylene (TCNE). Further, they showed that the ability to incorporate molecules within the pores also enables the synthesis of new crystalline phases and unlocks numerous applications, including gas sensing and photocatalysis, among others.
有机-无机杂化钙钛矿（HOIPs）因其独特的半导体特性在光电器件中的潜力而受到广泛研究。多孔HOIPs极为罕见，(APOSS)[CuCl]是极少数例子之一，其晶格中具有12 Å的孔。里德及其同事（C. W. 道尔顿、P. M. 甘农、W. 卡明斯基和D. A. 里德，《 》，2025年，DOI: https://doi.org/10.1039/D4SC04378B）最近揭示了这种有趣材料的结构，并证明这些孔可以容纳二茂铁（Fc）和四氰基乙烯（TCNE）等大型电活性分子。此外，他们表明在孔内纳入分子的能力还能够合成新的晶相，并开启了包括气体传感和光催化等在内的众多应用。
