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基于挖掘黄土合成的地质聚合物基PFSS的力学性能与微观结构

Mechanical Properties and Microstructure of Geopolymer-Based PFSS Synthesized from Excavated Loess.

作者信息

Chen Shujie, Zhang Hengchun, Yang Zhengzhou, Feng Chao, Wang Yao, Yu Demei, Fu Tengfei, Zhang Feng, Huang Xia

机构信息

College of Transportation and Civil Engineering, Fujian Agriculture and Forestry University, Fuzhou 350108, China.

CSCEC Strait Construction and Development Co., Ltd., Fuzhou 350015, China.

出版信息

Materials (Basel). 2024 Dec 25;18(1):30. doi: 10.3390/ma18010030.

Abstract

Pre-mixed fluidized solidified soil (PFSS) has the advantages of pumpability, convenient construction, and a short setting time. This paper took the excavated loess in Fuzhou as the research object and used cement-fly-ash-ground granulated blast furnace slag-carbide slag as a composite geopolymer system (CFGC) to synthesize PFSS. This study investigated the fluidity and mechanical strength of PFSS under different water-solid ratios and curing agent dosages; finally, the microstructure of the composite geopolymer system-pre-mixed fluidized solidified soil (CFGC-PFSS) was characterized. The results showed that when the water-solid ratio of PFSS increased from 0.46 to 0.54, the fluidity increased by 77 mm, and the flexural strength and compressive strength at 28 d decreased to 450.8 kPa and 1236.5 kPa. When the curing agent dosage increased from 15% to 25%, the fluidity increased by 18.0 mm, and the flexural strength and compressive strength at 28 d increased by 1.7 times and 1.6 times. A large number of needle-like AFt, C-S-H gel, and C-(A)-S-H gel coagulate with soil particles to form a three-dimensional reticular structure, which is the mechanism of the strength formation of PFSS under the action of CFGC.

摘要

预拌流态固化土(PFSS)具有可泵性好、施工方便、凝结时间短等优点。本文以福州原状黄土为研究对象,采用水泥-粉煤灰-磨细粒化高炉矿渣-电石渣作为复合地质聚合物体系(CFGC)来合成PFSS。本研究考察了不同水固比和固化剂掺量下PFSS的流动性和力学强度;最后,对复合地质聚合物体系-预拌流态固化土(CFGC-PFSS)的微观结构进行了表征。结果表明,当PFSS的水固比从0.46增加到0.54时,流动性增加了77mm,28d的抗折强度和抗压强度分别降至450.8kPa和1236.5kPa。当固化剂掺量从15%增加到25%时,流动性增加了18.0mm,28d的抗折强度和抗压强度分别提高了1.7倍和1.6倍。大量针状AFt、C-S-H凝胶和C-(A)-S-H凝胶与土颗粒凝聚形成三维网状结构,这是CFGC作用下PFSS强度形成的机理。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9141/11721838/b1768a199199/materials-18-00030-g001.jpg

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