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UiO-66金属有机框架膜：用于分离应用的结构工程

UiO-66 Metal-Organic Framework Membranes: Structural Engineering for Separation Applications.

作者信息

Sun Yanwei

机构信息

Faculty of Arts and Sciences, Beijing Normal University, Zhuhai 519087, China.

出版信息

Membranes (Basel). 2025 Jan 1;15(1):8. doi: 10.3390/membranes15010008.

DOI:10.3390/membranes15010008
PMID:39852249
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11767111/
Abstract

Metal-organic frameworks (MOFs) have been recognized as promising materials for membrane-based separation technologies due to their exceptional porosity, structural tunability, and chemical stability. This review presents a comprehensive discussion of the advancements in structure engineering and design strategies that have been employed to optimize UiO-66 membranes for enhanced separation performance. Various synthesis methods for UiO-66 membranes are explored, with a focus on modulated approaches that incorporate different modulators to fine-tune nucleation rates and crystallization processes. The influence of preferred orientation, membrane thickness, pore size, pore surface chemistry, and hierarchical structures on the separation performance is concluded. By providing a consolidated overview of current research efforts and future directions in UiO-66 membrane development, this review aims to inspire further advancements in the field of separation technologies.

摘要

金属有机框架材料（MOFs）因其优异的孔隙率、结构可调性和化学稳定性，已被公认为是基于膜的分离技术的有前途的材料。本文综述全面讨论了结构工程和设计策略方面的进展，这些进展已被用于优化UiO-66膜以提高分离性能。探索了UiO-66膜的各种合成方法，重点是采用不同调节剂来微调成核速率和结晶过程的调制方法。总结了择优取向、膜厚度、孔径、孔表面化学和分级结构对分离性能的影响。通过对UiO-66膜开发的当前研究工作和未来方向进行综合概述，本文综述旨在激发分离技术领域的进一步进展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/e0edace7ac71/membranes-15-00008-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/e35800e6be7f/membranes-15-00008-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/abb4308cef5b/membranes-15-00008-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/6baaa5fbb8e0/membranes-15-00008-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/e4715c977c66/membranes-15-00008-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/dfe6bed7c03d/membranes-15-00008-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/96e73bc470f5/membranes-15-00008-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/3228578afcbf/membranes-15-00008-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/3983482cad6e/membranes-15-00008-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/6fd621f0fabb/membranes-15-00008-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/e0edace7ac71/membranes-15-00008-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/e35800e6be7f/membranes-15-00008-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/abb4308cef5b/membranes-15-00008-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/6baaa5fbb8e0/membranes-15-00008-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/e4715c977c66/membranes-15-00008-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/dfe6bed7c03d/membranes-15-00008-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/96e73bc470f5/membranes-15-00008-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/3228578afcbf/membranes-15-00008-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/3983482cad6e/membranes-15-00008-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/6fd621f0fabb/membranes-15-00008-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0340/11767111/e0edace7ac71/membranes-15-00008-g010.jpg

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