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一次性口罩中的双酚A:一种新的人体暴露途径及其对水生环境的影响。

Bisphenol A in Disposable Face Masks: A Novel Human Exposure Pathway and Impact on the Aquatic Environment.

作者信息

Tse Hei-Tak, Au Chun-Kit, Chan Wan

机构信息

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong.

出版信息

Chem Res Toxicol. 2025 Feb 17;38(2):347-352. doi: 10.1021/acs.chemrestox.4c00535. Epub 2025 Feb 3.

Abstract

We identified and quantified bisphenol A (BPA), a known estrogen-like endocrine disruptor, in disposable face mask samples collected in Hong Kong. Results revealed that BPA is a common contaminant in face masks, with concentrations reaching up to 2 μg/mask. Although polypropylene, the primary material used in mask production, is generally considered to be BPA-free, the contaminant likely originates from additives, such as flame retardants, added during manufacturing. With a dermal absorption coefficient of 0.59 for BPA, the data indicate that mask-borne BPA is readily absorbed by the skin. Notably, 8 of 85 samples could cause the user to exceed the tolerable daily BPA intake set by the European Food Safety Agency (0.0002 μg/kg body weight per day). Additionally, BPA dissolves completely in landfill leachate in less than 70 days, which poses previously unrecognized health and environmental hazards. Given the extensive use of face masks during the pandemic, their role as personal protective equipment for medical practitioners, and the fact that there are currently no regulations regarding BPA contents in masks, it is imperative to investigate the need for regulations in order to safeguard face mask users and the environment.

摘要

我们在香港收集的一次性口罩样本中识别并量化了双酚A(BPA),一种已知的类似雌激素的内分泌干扰物。结果显示,BPA是口罩中的常见污染物,浓度高达每只口罩2微克。尽管口罩生产中使用的主要材料聚丙烯通常被认为不含BPA,但这种污染物可能源自制造过程中添加的添加剂,如阻燃剂。BPA的皮肤吸收系数为0.59,数据表明口罩携带的BPA很容易被皮肤吸收。值得注意的是,85个样本中有8个可能会导致使用者超过欧洲食品安全局设定的每日BPA耐受摄入量(每天每千克体重0.0002微克)。此外,BPA在不到70天的时间里就会在垃圾渗滤液中完全溶解,这带来了此前未被认识到的健康和环境危害。鉴于疫情期间口罩的广泛使用、它们作为医护人员个人防护装备的作用,以及目前尚无关于口罩中BPA含量的法规这一事实,为了保护口罩使用者和环境,调查是否需要制定法规势在必行。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b955/11837208/906ca2fa653a/tx4c00535_0001.jpg

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