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含酰肼-腙部分的新型偶氮染料用于聚酯织物染色。

Novel Azo dyes containing a hydrazide-hydrazone moiety for dyeing polyester fabric.

作者信息

Ali Ali A, Ismail Mostafa A, Elgammal Walid E, Belal Amany, Obaidullah Ahmed J, Khalil Ali Kh, Elhagali Gameel A M, El-Gaby Mohamed S A

机构信息

Department of Chemistry, Faculty of Science (Boys), Al-Azhar University, Nasr City, Cairo, 11884, Egypt.

Department of Chemistry, College of Science, King Khalid University, P. O. Box: 9004, 61413, Abha, Saudi Arabia.

出版信息

Sci Rep. 2025 Feb 5;15(1):4360. doi: 10.1038/s41598-024-83565-3.

Abstract

Novel azo dyes containing a hydrazide-hydrazone moiety linked to the benzothiazole nucleus are synthesized effectively in this study. The primary purpose of the study was to identify the best dyeing parameters, such as shade, temperature, pH, and time, in order to better understand the behaviour of dispersed dyes during polyester dyeing. To achieve excellent colour strength in value (K/S = 26), the ideal dyeing conditions for disperse dye 4 were 30 min, pH of 8, and 110 °C at shade 3%. While the ideal dyeing conditions for disperse dyes dye 10 and dye 11 were 30 min, pH of 2, and 130 °C at a shade of 3%. Depending on the coupler moieties, the coloured polyester samples ranged in hue from beige to dark brown. Furthermore, the impact of substituent's was examined in relation to colour strength (K/S) measures and colourimetric coordinates (CIELab*) of dyed polyester fabrics. The synthesized dispersed dyes are good options for giving polyester textiles a variety of stable hues and very good colour strength as well as exceptional fastness to light, washing, and crocking.

摘要

本研究有效地合成了含有与苯并噻唑核相连的酰肼腙部分的新型偶氮染料。该研究的主要目的是确定最佳染色参数,如色泽、温度、pH值和时间,以便更好地了解分散染料在聚酯染色过程中的行为。为了获得出色的色强度值(K/S = 26),分散染料4的理想染色条件为30分钟、pH值为8、在3%色泽下110°C。而分散染料10和染料11的理想染色条件为30分钟、pH值为2、在3%色泽下130°C。根据偶联剂部分的不同,染色后的聚酯样品的色调从米色到深棕色不等。此外,还研究了取代基对染色聚酯织物的色强度(K/S)测量值和色度坐标(CIELab*)的影响。合成的分散染料是使聚酯纺织品具有多种稳定色调、非常好的色强度以及出色的耐光、耐洗和摩擦牢度的良好选择。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cc3/11799431/edb761db1fb8/41598_2024_83565_Fig1_HTML.jpg

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