高效环保、无毒钙钛矿太阳能电池的设计与模拟

Design and simulation of a highly efficient eco-friendly, non-toxic perovskite solar cell.

作者信息

Ahathiyan G S, Du John H Victor, Moni D Jackuline, Sagayam K Martin, Pandey Binay Kumar, Pandey Digvijay, Lelisho Mesfin Esayas

机构信息

Division of Electronics and Communication Engineering, Karunya Institute of Technology and Sciences, Coimbatore, India.

Department of Information Technology, College of Technology, Govind Ballabh Pant University of Agriculture and Technology, Pantnagar, Uttrarakhand, India.

出版信息

Discov Nano. 2025 Feb 12;20(1):32. doi: 10.1186/s11671-025-04190-1.

DOI:10.1186/s11671-025-04190-1

PMID:39937384

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11822184/

Abstract

A highly efficient and nontoxic material methylammoniumtin(II) iodideperovskite solar cell is proposed. This proposed solar cell uses CHNHSnI as the absorber layer, TiO as an Electron transport layer (ETL), Indium tin oxide as a buffer layer, and Copper(I) oxide as the hole transport layer (HTL). The device is simulated using the SCAPS-1D simulation tool. This study details the optimization of a set of parameters, including the defect densities and the thickness of the absorber layer. The proposed structure is highly optimized result of 31.73% of enhanced power conversion efficiency (PCE), a J of 24.526 mA/cm (short-circuit current), FF of 81.40% (fill factor), and a V of 1.56 V (open-circuit voltage) is obtained through simulation process. Compared to previously reported works, the performance of the device has improved significantly due to better optimization. Along with this electrical characteristic temperature analyses, conductance voltage, capacitance-voltage, and bandgap analyses have also been carried out to examine the device's efficiency and performance.

摘要

提出了一种高效且无毒的材料——甲基碘化亚锡钙钛矿太阳能电池。该太阳能电池采用CHNHSnI作为吸收层，TiO作为电子传输层（ETL），氧化铟锡作为缓冲层，氧化亚铜作为空穴传输层（HTL）。使用SCAPS - 1D模拟工具对该器件进行模拟。本研究详细介绍了一组参数的优化，包括缺陷密度和吸收层的厚度。通过模拟过程，所提出的结构实现了31.73%的功率转换效率（PCE）提高、24.526 mA/cm的短路电流密度（J）、81.40%的填充因子（FF）以及1.56 V的开路电压（V），是高度优化的结果。与先前报道的工作相比，由于优化效果更好，该器件的性能有了显著提升。除了这种电学特性分析外，还进行了电导电压、电容电压和带隙分析，以检验该器件的效率和性能。