Chen Xue-Qiang, Xie Lina, Fang Shiqiang, Hu Wenjing, Cao Ming
Centre for the Protection of Cultural Property, Ningbo University of Finance and Economics, Ningbo, 315175, China.
Sci Rep. 2025 Mar 24;15(1):10044. doi: 10.1038/s41598-025-95458-0.
Ensuring the preservation of fragile artifacts from waterlogged archaeological sites demands the advancement of extraction techniques that uphold both safety and the integrity of historical data. Conventionally employed extraction materials are predominantly applicable to sites exhibiting high soil stability and low moisture content, whereas the recovery of artifacts from waterlogged contexts remains technically challenging. This study explores low-acyl gellan gum as a temporary solidification material for waterlogged archaeological relics, enhancing its efficacy through ionic cross-linking methodologies. The results show that by meticulously regulating the species and concentration of cations-specifically Na, Mg, Ca, or Al- an improvement in gelling strength can be attained within an optimum range. The gel strength improved with the increase of ion valence, but adding Al results in local gel aggregation. By adding 3.0 wt% of CaCl, low-acyl gellan gum can form a transparent, stable gel with a compressive strength amplified to 0.11 MPa. In addition, the temporary consolidation and extraction experiment under laboratory conditions shows that Ca cross-linked gellan gum can effectively carry out temporary solidification and safe extraction of multiple artifacts at waterlogged archaeological sites. This innovation presents a simplified yet potent strategy for excavating fragile artifacts.
确保从水淹考古遗址中保存脆弱文物需要改进提取技术,以维护安全性和历史数据的完整性。传统使用的提取材料主要适用于土壤稳定性高且含水量低的遗址,而从水淹环境中回收文物在技术上仍然具有挑战性。本研究探索了低酰基结冷胶作为水淹考古文物的临时固化材料,并通过离子交联方法提高其功效。结果表明,通过精心调节阳离子(特别是Na、Mg、Ca或Al)的种类和浓度,可以在最佳范围内提高凝胶强度。凝胶强度随离子价态的增加而提高,但添加Al会导致局部凝胶聚集。通过添加3.0 wt%的CaCl₂,低酰基结冷胶可以形成透明、稳定的凝胶,抗压强度提高到0.11 MPa。此外,实验室条件下的临时固结和提取实验表明,Ca交联的结冷胶可以有效地对水淹考古遗址的多件文物进行临时固化和安全提取。这一创新为挖掘脆弱文物提供了一种简单而有效的策略。