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使用碳纳米点和天然染料的增强型格拉茨尔太阳能电池。

Enhanced Grätzel Solar Cells Using Carbon Nanodots and Natural Dye.

作者信息

Amancio Moisés do Amaral, Barcelay Yonny Romaguera, Gandarilla Ariamna, Sales Ronald Rastre, de Souza Thiago Monteiro, Nobre Francisco Xavier, Raphael Ellen, Brito Walter Ricardo

机构信息

LABEL-Laboratório de Bioeletrônica e Eletroanalítica (LABEL), Department of Chemistry, Federal University of Amazonas, Manaus 69067-005, Amazonas, Brazil.

BioMark@UC/CEMMPRE-ARISE, Department of Chemical Engineering, Faculty of Science and Technology, University of Coimbra, Coimbra 3030-790, Portugal.

出版信息

ACS Phys Chem Au. 2024 Dec 16;5(2):151-161. doi: 10.1021/acsphyschemau.4c00080. eCollection 2025 Mar 26.

Abstract

Photoluminescent carbon nanodots have shown great potential in various scientific fields, with prominence in technological applications. Their low toxicity, affordability, and biocompatibility make them a promising alternative in developing next-generation solar cells. This study explored carbon nanodots (CNDs) as an alternative to traditional carbon allotropes, focusing on creating sustainable and environmentally friendly Grätzel-type solar cells using low-cost materials. The feasibility of CNDs, in conjunction with fruit dye as TiO sensitizers, was investigated, as well as the impact on the diffusion coefficient of I in the electrolyte due to excess I. The synergistic interaction between the dye and CNDs altered the material energy states, red-shifting the solution's light absorption region (Dye-CNDs). Improved and values were recorded, and as a result, a 5% increase in energy conversion efficiency (η) was calculated for the FTO/TiO-Dye-CNDs photoanode cell compared to the control photoanode cell (FTO/TiO-Dye). These results highlight the promising potential of CNDs as a low-cost alternative to significantly enhance the potential of Grätzel-type solar cells, paving the way for more sustainable energy solutions.

摘要

光致发光碳纳米点在各个科学领域都显示出了巨大的潜力,在技术应用方面尤为突出。它们的低毒性、低成本和生物相容性使其成为开发下一代太阳能电池的有前途的替代品。本研究探索了碳纳米点(CNDs)作为传统碳同素异形体的替代品,重点是使用低成本材料制造可持续且环保的格拉茨尔型太阳能电池。研究了碳纳米点与水果染料作为二氧化钛敏化剂的可行性,以及过量碘对电解质中碘扩散系数的影响。染料与碳纳米点之间的协同相互作用改变了材料的能量状态,使溶液的光吸收区域发生红移(染料-碳纳米点)。记录到了改善的[具体参数1]和[具体参数2]值,结果表明,与对照光阳极电池(FTO/TiO-染料)相比,FTO/TiO-染料-碳纳米点光阳极电池的能量转换效率(η)提高了5%。这些结果突出了碳纳米点作为低成本替代品的巨大潜力,可显著提高格拉茨尔型太阳能电池的性能,为更可持续的能源解决方案铺平道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/029e/11950868/c5a70e6b1253/pg4c00080_0001.jpg

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