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生物质的催化热解:沸石、碳质和金属氧化物催化剂综述

Catalytic Pyrolysis of Biomass: A Review of Zeolite, Carbonaceous, and Metal Oxide Catalysts.

作者信息

Sun Weiqiang, Yan Yihong, Wei Yuxin, Ma Jingjing, Niu Zhenchuan, Hu Guang

机构信息

School of Nuclear Science and Technology, Xi'an Jiaotong University, Xi'an 710049, China.

School of Human Settlements and Civil Engineering, Xi'an Jiaotong University, Xi'an 710049, China.

出版信息

Nanomaterials (Basel). 2025 Mar 26;15(7):493. doi: 10.3390/nano15070493.

Abstract

This review provides an exploration of various catalytic pyrolysis techniques for bio-oil production, focusing on the effects of different pyrolysis methods (slow, fast, and flash pyrolysis) on bio-oil yield and composition. The review also discusses key factors influencing bio-oil production, including feedstock composition (cellulose, hemicellulose, and lignin), and the role of catalytic materials in enhancing yield and product selectivity. Three primary classes of catalysts-zeolites, carbonaceous materials, and metal oxides-are thoroughly examined, with a discussion on the differences between bulk catalysts and nanocatalysts. The paper highlights how these catalysts influence the formation of bio-oil components such as phenols, hydrocarbons, and oxygenated compounds. Furthermore, this review discusses recent advancements in catalyst design and modifications to optimize bio-oil production. This review provides the latest advancements in catalytic pyrolysis, emphasizing the correlation between catalyst properties and the resulting products. It aims to offer valuable insights into the future potential of catalytic pyrolysis for efficient biomass conversion and sustainable biofuel production.

摘要

本综述探讨了用于生物油生产的各种催化热解技术,重点关注不同热解方法(慢速、快速和闪速热解)对生物油产率和组成的影响。该综述还讨论了影响生物油生产的关键因素,包括原料组成(纤维素、半纤维素和木质素),以及催化材料在提高产率和产物选择性方面的作用。对三类主要催化剂——沸石、碳质材料和金属氧化物——进行了全面研究,并讨论了块状催化剂和纳米催化剂之间的差异。本文强调了这些催化剂如何影响生物油成分如酚类、烃类和含氧化合物的形成。此外,本综述讨论了催化剂设计和改性方面的最新进展,以优化生物油生产。本综述介绍了催化热解的最新进展,强调了催化剂性能与所得产物之间的相关性。其目的是为催化热解在高效生物质转化和可持续生物燃料生产方面的未来潜力提供有价值的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4461/11990603/7459376cdc3e/nanomaterials-15-00493-g002.jpg

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