Mu Junjie, Hou Jinfeng, Qiu Shaoqi, Qiao Shunda, He Ying, Ma Yufei
National Key Laboratory of Laser Spatial Information, Harbin Institute of Technology, Harbin 150001, China.
Zhengzhou Research Institute, Harbin Institute of Technology, Zhengzhou 450008, China.
Sensors (Basel). 2025 Mar 27;25(7):2099. doi: 10.3390/s25072099.
A carbon dioxide (CO) sensor based on light-induced thermoelastic spectroscopy (LITES) using a 2 μm diode laser and a self-designed low-frequency trapezoidal-head QTF is reported for the first time in this invited paper. The self-designed trapezoidal-head QTF with a low resonant frequency of 9464.18 Hz and a high quality factor () of 12,133.56 can significantly increase the accumulation time and signal level of the CO-LITES sensor. A continuous-wave (CW) distributed-feedback (DFB) diode laser is used as the light source, and the strongest absorption line of CO located at 2004.01 nm is chosen. A comparison between the standard commercial QTF with the resonant frequency of 32.768 kHz and the self-designed trapezoidal-head QTF is performed. The experimental results show that the CO-LITES sensor with the self-designed trapezoidal-head QTF has an excellent linear response to CO concentration, and its minimum detection limit (MDL) can reach 46.08 ppm (parts per million). When the average time is increased to 100 s based on the Allan variance analysis, the MDL of the sensor can be improved to 3.59 ppm. Compared with the 16.85 ppm of the CO-LITES sensor with the commercial QTF, the performance is improved by 4.7 times, demonstrating the superiority of the self-designed trapezoidal-head QTF.
在这篇特邀论文中,首次报道了一种基于光致热弹性光谱(LITES)的二氧化碳(CO)传感器,该传感器使用了2μm二极管激光器和自行设计的低频梯形头石英晶体微天平(QTF)。自行设计的梯形头QTF具有9464.18Hz的低谐振频率和12133.56的高品质因数(),可显著增加CO-LITES传感器的累积时间和信号电平。使用连续波(CW)分布反馈(DFB)二极管激光器作为光源,并选择位于2004.01nm处的CO最强吸收线。对谐振频率为32.768kHz的标准商用QTF和自行设计的梯形头QTF进行了比较。实验结果表明,采用自行设计的梯形头QTF的CO-LITES传感器对CO浓度具有优异的线性响应,其最低检测限(MDL)可达46.08ppm(百万分之一)。基于阿伦方差分析,当平均时间增加到100s时,传感器的MDL可提高到3.59ppm。与采用商用QTF的CO-LITES传感器的16.85ppm相比,性能提高了4.7倍,证明了自行设计的梯形头QTF的优越性。