Wasilewska Anna, Basa Anna, Zambrzycka Monika, Swiecicka Izabela, Kalska-Szostko Beata
Doctoral School of University of Bialystok, Ciolkowskiego 1K, 15-245 Bialystok, Poland.
Faculty of Chemistry, University of Bialystok, Ciolkowskiego 1K, 15-245 Bialystok, Poland.
Nanomaterials (Basel). 2025 Apr 12;15(8):595. doi: 10.3390/nano15080595.
Nowadays, there is a growing need to develop environmentally friendly procedures that reduce the use of toxic chemicals in synthesis. Green synthesis methods have an advantage over conventional chemical methods because they do not pollute the environment significantly. This has generated more interest in using readily available plants to create nanomaterials. In this work, silver nanoparticles were obtained through green chemistry using natural reducing agents present in apple extract. The research focused on optimizing the synthesis conditions to obtain predictable structures. The characterization of the nanoparticles was performed using transmission electron microscopy (TEM), dynamic light scattering (DLS), X-ray diffraction (XRD), UV-Vis spectroscopy, and infrared spectroscopy (IR). The achieved results led to the conclusion that the use of apple extract was suitable for obtaining homogenous and spherical silver nanoparticles at a wide range of core precursor concentrations and a variable pH. The diameter of the studied nanoparticles ranged from 6 to 22 nm. The nanoparticles obtained with apple extract were highly active against Gram-positive bacteria and fungus, but less active against Gram-negative bacteria. The development of nanotechnology in green chemistry processes will gradually increase with technological advances, being a key component in developing new synthesis processes for nano-object formation.
如今,开发环境友好型程序以减少合成过程中有毒化学品的使用需求日益增长。绿色合成方法相较于传统化学方法具有优势,因为它们对环境的污染较小。这使得利用易于获取的植物来制备纳米材料更受关注。在这项工作中,通过绿色化学利用苹果提取物中存在的天然还原剂获得了银纳米颗粒。该研究聚焦于优化合成条件以获得可预测的结构。使用透射电子显微镜(TEM)、动态光散射(DLS)、X射线衍射(XRD)、紫外可见光谱和红外光谱(IR)对纳米颗粒进行了表征。所取得的结果得出结论,在广泛的核心前驱体浓度和可变pH值下,使用苹果提取物适合获得均匀且呈球形的银纳米颗粒。所研究的纳米颗粒直径范围为6至22纳米。用苹果提取物获得的纳米颗粒对革兰氏阳性菌和真菌具有高活性,但对革兰氏阴性菌的活性较低。随着技术进步,绿色化学过程中纳米技术的发展将逐渐增加,成为开发用于纳米物体形成的新合成过程的关键组成部分。