Silva Ana Catarina, Rocha Pedro, Valderrama Patrícia, Antelo Juan, Geraldo Dulce, Proença Maria Fernanda, Fiol Sarah, Bento Fátima
Department of Chemistry, Centre of Chemistry, University of Minho, Campus Gualtar, 4710-057 Braga, Portugal.
CRETUS, Cross-Disciplinary Research in Environmental Technologies, Department of Physical Chemistry, University of Santiago de Compostela, 15782 Santiago de Compostela, Spain.
Molecules. 2025 Mar 28;30(7):1511. doi: 10.3390/molecules30071511.
The efficient characterization of compost quality is essential for optimizing its application in agriculture and soil improvement. In this study, a correlation-based approach was employed to evaluate relationships between physicochemical properties, structural features, and reactivity indicators of compost extracts-fulvic acid-like (FA-L), humic acid-like (HA-L), and dissolved organic matter (DOM)-and their respective bulk composts. The goal was to identify key compost parameters that can serve as reliable predictors of humic substance composition and bioactivity, thereby reducing reliance on labor-intensive humic substance extractions. A comprehensive set of elemental, spectroscopic (UV-vis, ATR-FTIR, H-NMR), and thermal (TGA-DSC) analyses were conducted to assess the composition and stability of the extracts. Strong correlations were found between compost oxidation state (/), cation exchange capacity (), thermal stability, and the structural characteristics of humic substances-like (HS-L) fractions, suggesting that direct compost characterization can effectively predict humic substance reactivity and agronomic potential. The findings also align with a previously developed Compost Quality Index (CQI), reinforcing the functional role of humic substances in soil fertility and nutrient retention. By establishing a simplified yet robust compost assessment framework, this study advances the potential for efficient, cost-effective evaluation methodologies for compost quality.
堆肥质量的有效表征对于优化其在农业和土壤改良中的应用至关重要。在本研究中,采用了一种基于相关性的方法来评估堆肥提取物(类富里酸(FA-L)、类胡敏酸(HA-L)和溶解有机物(DOM))的物理化学性质、结构特征和反应性指标与其各自的堆肥主体之间的关系。目标是确定可作为腐殖质组成和生物活性可靠预测指标的关键堆肥参数,从而减少对劳动密集型腐殖质提取的依赖。进行了一系列全面的元素分析、光谱分析(紫外可见光谱、衰减全反射傅里叶变换红外光谱、氢核磁共振光谱)和热分析(热重分析-差示扫描量热法),以评估提取物的组成和稳定性。发现堆肥氧化态(/)、阳离子交换容量()、热稳定性与类腐殖质(HS-L)组分的结构特征之间存在强相关性,这表明直接对堆肥进行表征可以有效预测腐殖质的反应性和农艺潜力。研究结果还与先前开发的堆肥质量指数(CQI)一致,强化了腐殖质在土壤肥力和养分保持中的功能作用。通过建立一个简化但稳健的堆肥评估框架,本研究提高了高效、经济有效的堆肥质量评估方法的潜力。