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淀粉生物塑料作为一种可持续包装替代品的开发与特性研究

Development and characterization of starch bioplastics as a sustainable alternative for packaging.

作者信息

Gurunathan Manoj Kumar, Navasingh Rajesh Jesudoss Hynes, Selvam Jebaraj David Raja, Čep Robert

机构信息

Department of Mechanical Engineering, Mepco Schlenk Engineering College, Sivakasi, 626005, Tamil Nadu, India.

Faculty of Mechanical Engineering, Opole University of Technology, Proszkowska 76, Opole, 45-758, Poland.

出版信息

Sci Rep. 2025 May 1;15(1):15264. doi: 10.1038/s41598-025-00221-0.

Abstract

Due to the growing environmental concerns of petroleum-based plastics, there has been a surge of interest in biodegradable alternatives. In this study, starch-based bioplastic was prepared using biopolymers extracted from corn and potato and the biopolymer was mixed with calcium carbonate (filler) and plasticizers (glycerol-sorbitol) and evaluated. For the fabricated formulation, Taguchi analysis gave an optimal formulation of 9 g corn starch, 9 mL glycerol, and 2.5 g calcium carbonate, having a well-balanced mechanical strength, flexibility, and biodegradability. The results showed a major improvement in tensile strength of 22.5% (6.08 MPa) and a 31.7% increase in Young's modulus (0.103 GPa), compared to the least effective sample. In biodegradation tests, the degradation rate of C1 (66.68%) was the fastest, while C3 had a slower rate (29.08%). Moisture absorption varied considerably, with sample COM3 absorbing 25.92% compared to just 4.35% for P3, while P3 absorbed only 4.35%. Among compounds, the higher and lower percentage for water solubility were for P1 (20.50%) and C3 (49.04%) respectively. These results underscore the potential of starch-based bioplastics for sustainable packaging, offering an environmentally friendly option compared to traditional plastics.

摘要

由于对石油基塑料的环境问题日益关注,人们对可生物降解替代品的兴趣激增。在本研究中,使用从玉米和土豆中提取的生物聚合物制备了淀粉基生物塑料,并将该生物聚合物与碳酸钙(填料)和增塑剂(甘油 - 山梨醇)混合并进行评估。对于制成的配方,田口分析得出最佳配方为9克玉米淀粉、9毫升甘油和2.5克碳酸钙,其具有平衡良好的机械强度、柔韧性和生物降解性。结果表明,与效果最差的样品相比,拉伸强度有22.5%(6.08兆帕)的显著提高,杨氏模量增加了31.7%(0.103吉帕)。在生物降解测试中,C1的降解率(66.68%)最快,而C3的降解率较慢(29.08%)。吸湿情况差异很大,样品COM3吸湿25.92%,而P3仅吸湿4.35%。在化合物中,水溶性的较高和较低百分比分别为P1(20.50%)和C3(49.04%)。这些结果强调了淀粉基生物塑料用于可持续包装的潜力,与传统塑料相比提供了一种环保选择。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a95/12046032/502ec28e892b/41598_2025_221_Fig1_HTML.jpg

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