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基于锆羧酸盐超分子组装体的拟肽配位聚合物

Pseudopeptidic Coordination Polymers Based on Zirconium-Carboxylate Supramolecular Assemblies.

作者信息

Maireles-Porcar Miguel, Esteve Ferran, Martín Nuria, Sanchez-Velandia Julián, Altava Belén, Cirujano Francisco G, García-Verdugo Eduardo

机构信息

Departamento de Química Inorgánica y Orgánica, Universitat Jaume I, Av. Vicent Sos Baynat, s/n, 12006 Castelló de la Plana, Castelló, España.

Laboratoire de Chimie Supramoléculaire, Institut de Science et d'Ingénierie Supramoléculaires (ISIS), Université de Strasbourg, 8 allée Gaspard Monge, 6700 Strasbourg, France.

出版信息

ACS Appl Mater Interfaces. 2025 May 14;17(19):28555-28567. doi: 10.1021/acsami.5c02827. Epub 2025 May 5.

DOI:10.1021/acsami.5c02827
PMID:40320902
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12129261/
Abstract

Mimicking enzymes with new materials is a promising approach to improve efficiency and sustainability in heterogeneous catalysis. In this contribution, a family of coordination polymers based on , '-bis(amino acid)pyromellitic diimide linkers and Zr-oxo clusters has been assembled under solvothermal conditions in the presence of different acids (acetic, hydrochloric, and formic acid). The linker has been prepared from widely available amino acids and pyromellitic anhydride under microwave conditions. Different characterization techniques, such as NMR, Fourier transform infrared spectroscopy (FTIR), TGA, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM)/EDX, confirmed the formation of the pseudopeptidic (PSP) linkers and the subsequent formation of Zr-carboxylate bonds in the Zr-PSP coordination polymer, forming regular homogeneous nanoparticles with hybrid inorganic-organic composition. The PSPs have also been incorporated into defective UiO-67 crystals and employed as catalysts in the hydrolysis of -nitrophenylacetate under mild conditions, exhibiting a correlation between porosity, residue volume, and activity.

摘要

用新材料模拟酶是提高多相催化效率和可持续性的一种有前景的方法。在本论文中，基于，'-双（氨基酸）均苯四甲酸二酰亚胺连接体和锆氧簇的一系列配位聚合物在不同酸（乙酸、盐酸和甲酸）存在下于溶剂热条件下组装而成。连接体是在微波条件下由广泛可得的氨基酸和均苯四甲酸酐制备的。不同的表征技术，如核磁共振（NMR）、傅里叶变换红外光谱（FTIR）、热重分析（TGA）、X射线光电子能谱（XPS）和扫描电子显微镜（SEM）/能谱分析（EDX），证实了拟肽（PSP）连接体的形成以及随后在Zr-PSP配位聚合物中锆-羧酸盐键的形成，形成了具有无机-有机混合组成的规则均匀纳米颗粒。PSP还被引入到有缺陷的UiO-67晶体中，并在温和条件下用作对硝基苯乙酸水解的催化剂，表现出孔隙率、残留体积和活性之间的相关性。

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本文引用的文献

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