Manca Nicola, Plaza Alejandro E, Cichetto Leonélio, Venstra Warner J, Bernini Cristina, Marré Daniele, Pellegrino Luca
CNR-SPIN, C.so F. M. Perrone, 24, Genova, 16152, Italy.
RAISE Ecosystem, Genova, 16122, Italy.
Adv Sci (Weinh). 2025 May;12(20):e2412683. doi: 10.1002/advs.202412683. Epub 2025 May 8.
Suspended micro-structures made of epitaxial complex oxides rely on surface micro-machining processes based on sacrificial layers. These processes prevent to physically access the microstructures from both sides, as substantial part of the substrate is not removed. In this work, a bulk micromachining protocol is developed for a commonly used substrate employed in oxide thin films deposition. Suspended oxide thin film devices are realized by fabricating pass-through holes across SrTiO(100) or SrTiO(110) substrates. Careful calibration of anisotropic etching rates allows controlling the final geometry of the aperture in the substrate in a predictable way. As demonstrators of possible device geometries, clamped membranes and trampolines realized from deposited thin films of (La,Sr)MnO, a conductive magnetic oxide, and a suspended trampoline resonator carved from the SrTiO substrate itself are presented. Reported protocols can be readily applied to a broad variety of other complex oxides so to extend the use of membranes technology beyond those of commercially available silicon compounds.
由外延复合氧化物制成的悬浮微结构依赖于基于牺牲层的表面微加工工艺。这些工艺阻碍了从两侧对微结构进行物理访问,因为大部分衬底未被去除。在这项工作中,针对氧化物薄膜沉积中常用的衬底开发了一种体微加工方案。通过在SrTiO(100)或SrTiO(110)衬底上制造通孔来实现悬浮氧化物薄膜器件。对各向异性蚀刻速率的仔细校准使得能够以可预测的方式控制衬底中孔径的最终几何形状。作为可能的器件几何形状的示例,展示了由导电磁性氧化物(La,Sr)MnO的沉积薄膜制成的夹紧膜和蹦床,以及由SrTiO衬底本身雕刻而成的悬浮蹦床谐振器。所报道的方案可以很容易地应用于多种其他复合氧化物,从而将膜技术的应用扩展到商业可用硅化合物之外。