Scalable Production and Multifunctional Coating of Gold Nanostars for Catalytic Applications.

Gold nanostars (AuNSTs) stabilized with adenosine monophosphate (AMP) were synthesized using a scalable method, achieving a 30-fold yield increase compared to previous studies using AMP as a shaping agent, while also reducing the reaction time to 3 h. The AuNSTs were coated with mesoporous silica (mSiO) via a robust approach, producing the AuNSTs@mSiO nanoparticles (NPs) with tunable thicknesses and consistent optical properties for a range of morphologies. The NPs were additionally coated with platinum (Pt) before synthesizing the mSiO layer, facilitating a comparative analysis of catalytic activity. The catalytic performance of the bare AuNSTs, the AuNSTs@mSiO, and the AuNSTs@Pt@mSiO was evaluated through methylene blue reduction, confirming the gold core as the primary catalytic source. The AuNSTs@Pt@mSiO exhibited enhanced activity, highlighting the potential of the mSiO coatings. Additionally, solid-phase catalytic tests using 3,3',5,5'-tetramethylbenzidine (TMB) on cellulose discs demonstrated the effectiveness of these NPs under diverse conditions. These findings showcase the versatility and broad catalytic potential of silica-coated NPs for solution- and solid-phase applications.