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具有尺寸可控颜色可调白光发射的单片式氮化镓基双量子阱发光二极管。

Monolithic GaN-Based Dual-Quantum-Well LEDs with Size-Controlled Color-Tunable White-Light Emission.

作者信息

Lee Seung Hun, Jeon Dabin, Lee Gun-Woo, Lee Sung-Nam

机构信息

Department of IT Semiconductor Convergence Engineering, Tech University of Korea, Siheung 15073, Republic of Korea.

Department of Semiconductor Engineering, Tech University of Korea, Siheung 15073, Republic of Korea.

出版信息

Materials (Basel). 2025 May 6;18(9):2140. doi: 10.3390/ma18092140.

Abstract

We report a monolithic GaN-based light-emitting diode (LED) platform capable of color-tunable white-light emission via LED size scaling. By varying the LED size from 800 µm to 50 µm, the injection current density was effectively controlled under constant driving current, enabling precise modulation of carrier distribution within a dual-composition multi-quantum well (MQW) structure. The active layer consists of five lower InGaN/GaN QWs for blue emission and strain induction, and an upper InGaN/GaN single QW engineered for red-orange emission. The strain imposed by lower QWs promotes indium segregation in the last QW through spinodal decomposition, resulting in a broadened emission spanning from ~500 nm to 580 nm. High-resolution TEM and EDX analyses directly confirmed the indium segregation and phase-separated structure of the last QW. Spectral analysis revealed that larger devices exhibited dominant emission at 580 nm with a correlated color temperature (CCT) of 2536 K and a CIE coordinate of (0.501, 0.490). As LED size decreased, increased hole injection allowed recombination to occur in deeper QWs, resulting in a blueshift to 450 nm and a CCT of 9425 K with CIE (0.224, 0.218) in the 50 × 50 µm LED. This approach enables phosphor-free white-light generation with tunable color temperatures and chromaticities using a single wafer, offering a promising strategy for compact, adaptive solid-state lighting applications.

摘要

我们报道了一种基于氮化镓的单片发光二极管(LED)平台,该平台能够通过LED尺寸缩放实现颜色可调的白光发射。通过将LED尺寸从800 µm变化到50 µm,在恒定驱动电流下有效控制了注入电流密度,从而能够精确调制双组分多量子阱(MQW)结构内的载流子分布。有源层由五个用于蓝光发射和应变诱导的下部InGaN/GaN量子阱以及一个设计用于红橙色发射的上部InGaN/GaN单量子阱组成。下部量子阱施加的应变通过旋节分解促进了最后一个量子阱中的铟偏析,导致发射光谱展宽,范围从~500 nm到580 nm。高分辨率透射电子显微镜(TEM)和能谱分析(EDX)直接证实了最后一个量子阱中的铟偏析和相分离结构。光谱分析表明,较大尺寸的器件在580 nm处表现出主导发射,相关色温(CCT)为2536 K,CIE坐标为(0.501, 0.490)。随着LED尺寸减小,空穴注入增加,使得复合发生在更深的量子阱中,并导致蓝移至450 nm,在尺寸为50×50 µm的LED中,CCT为9425 K,CIE坐标为(0.224, 0.218)。这种方法能够使用单个晶片产生具有可调色温和色度的无磷白光,为紧凑、自适应固态照明应用提供了一种有前景的策略。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ad9/12072864/0e213250f8b7/materials-18-02140-g001.jpg

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