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掺杂无机纳米粒子的低密度聚乙烯的工频击穿特性

Power Frequency Breakdown Properties of LDPE-Doped Inorganic Nanoparticles.

作者信息

Cheng Yujia, Yu Guang

机构信息

Mechanical and Electrical Engineering Institute, University of Electronic Science and Technology of China Zhongshan Institute, Zhongshan 528400, China.

出版信息

Molecules. 2025 Apr 25;30(9):1914. doi: 10.3390/molecules30091914.

DOI:10.3390/molecules30091914
PMID:40363719
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12073233/
Abstract

Although polyethylene is widely used in electrical insulation, it does not possess dielectric properties. It is therefore desirable to develop insulation materials with excellent dielectric properties. In this study, low-density polyethylene (LDPE) was used as a matrix resin, while MgO, wollastonite, and montmorillonite (MMT) were employed as inorganic nano-additives. Three composites were prepared using the boiling-melt blending approach. Power frequency breakdown tests were performed on the original LDPE and on the prepared nanoparticle/LDPE composites. Upon combination with the Weibull distribution, the breakdown test results revealed that the addition of these nano-additive particles to the LDPE matrix increased the breakdown field strength of the material. The highest breakdown field strength for the nano-MgO/LDPE composite was obtained using a MgO loading of 0.5%. Notably, the obtained value was 1.8% higher than that of the pure LDPE. In addition, the highest breakdown field strength for the nano-wollastonite/LDPE composite was obtained using a wollastonite loading of 1% (7.48% higher than that of pure LDPE). Similarly, the highest breakdown field strength of the nano-MMT/LDPE composite was obtained using an MMT loading of 3%, giving a value that was 6.67% higher than that of the pure LDPE.

摘要

尽管聚乙烯广泛应用于电气绝缘领域,但它并不具备介电性能。因此,开发具有优异介电性能的绝缘材料是很有必要的。在本研究中,低密度聚乙烯(LDPE)被用作基体树脂,而氧化镁、硅灰石和蒙脱石(MMT)则被用作无机纳米添加剂。采用沸腾熔融共混法制备了三种复合材料。对原始LDPE和制备的纳米颗粒/LDPE复合材料进行了工频击穿试验。结合威布尔分布,击穿试验结果表明,向LDPE基体中添加这些纳米添加剂颗粒提高了材料的击穿场强。纳米氧化镁/LDPE复合材料在氧化镁负载量为0.5%时获得了最高击穿场强。值得注意的是,该值比纯LDPE高出1.8%。此外,纳米硅灰石/LDPE复合材料在硅灰石负载量为1%时获得了最高击穿场强(比纯LDPE高7.48%)。同样,纳米MMT/LDPE复合材料在MMT负载量为3%时获得了最高击穿场强,该值比纯LDPE高6.67%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/20bf0cd89885/molecules-30-01914-g013.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/1b30e98c511b/molecules-30-01914-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/c3c36847dfa5/molecules-30-01914-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/0fda8031c3ee/molecules-30-01914-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/c14e2204469e/molecules-30-01914-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/68a8baad7c01/molecules-30-01914-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/564bdaf2b6fc/molecules-30-01914-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/20bf0cd89885/molecules-30-01914-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/3e09c48cbe11/molecules-30-01914-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/0b1e0b32cd1c/molecules-30-01914-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/a55058f7e12f/molecules-30-01914-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/a7e0241bd9d2/molecules-30-01914-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/8e2343178b14/molecules-30-01914-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/035822d82907/molecules-30-01914-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/1b30e98c511b/molecules-30-01914-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/c3c36847dfa5/molecules-30-01914-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/0fda8031c3ee/molecules-30-01914-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/c14e2204469e/molecules-30-01914-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/68a8baad7c01/molecules-30-01914-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/564bdaf2b6fc/molecules-30-01914-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d245/12073233/20bf0cd89885/molecules-30-01914-g013.jpg

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