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铜掺杂的氧化锌纳米颗粒及其在罗丹明B光催化降解中的应用。

Cu-doped ZnO nanoparticles and its application for the photocatalytic degradation of Rhodamine B.

作者信息

Chen Guijuan, Yang Miao, Tian Beibei, Yao Jun, Chen Songlin, Li Deming, Yuan Guojun

机构信息

Anhui Vocational and Technical College, Collaborative Innovation Center for Chemistry and Life Sciences, Hefei, 230011, China.

出版信息

Sci Rep. 2025 May 25;15(1):18246. doi: 10.1038/s41598-025-02432-x.

Abstract

Rhodamine B (RhB), a dye with high environmental pollution risks, necessitates effective degradation strategies for environmental protection. Photocatalytic degradation technology offers a viable solution to mitigate such pollution, with ZnO being extensively utilized in dye degradation due to its excellent ultraviolet (UV) photocatalytic performance. In this study, Cu-doped ZnO nanoparticles were successfully synthesized via a facile method. When the Cu doping level was 0.5%, the material exhibited remarkable photocatalytic activity under UV irradiation, achieving complete RhB degradation within 2 h (degradation efficiency up to 100%). The physical and chemical properties of the material were systematically analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results indicated that Cu incorporation did not alter the crystallinity of ZnO but significantly enhanced its light response capability. Based on the experimental results of UV-catalyzed RhB solution degradation, the photocatalytic mechanism of Cu-doped ZnO was thoroughly investigated, providing theoretical insights and technical support for the development of high-efficiency photocatalysts for dye degradation.

摘要

罗丹明B(RhB)是一种具有高环境污染风险的染料,需要有效的降解策略来保护环境。光催化降解技术为减轻此类污染提供了一种可行的解决方案,由于其优异的紫外(UV)光催化性能,氧化锌被广泛用于染料降解。在本研究中,通过一种简便的方法成功合成了铜掺杂的氧化锌纳米颗粒。当铜掺杂水平为0.5%时,该材料在紫外光照射下表现出显著的光催化活性,在2小时内实现了罗丹明B的完全降解(降解效率高达100%)。使用X射线衍射(XRD)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对该材料的物理和化学性质进行了系统分析。结果表明,铜的掺入并没有改变氧化锌的结晶度,但显著提高了其光响应能力。基于紫外光催化罗丹明B溶液降解的实验结果,深入研究了铜掺杂氧化锌的光催化机理,为开发高效染料降解光催化剂提供了理论见解和技术支持。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe79/12104330/7da29f4afcff/41598_2025_2432_Fig1_HTML.jpg

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