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响应性工业聚合物:聚氨酯与液晶弹性体的结合?

Responsive Industrial Polymers: A Marriage of Polyurethanes with Liquid Crystal Elastomers?

作者信息

Yue Lansong, Wan Xue, Türel Tankut, Schenning Albert P H J, Tomović Željko, Debije Michael G

机构信息

Stimuli-Responsive Functional Materials and Devices, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, Eindhoven 5600 MB, The Netherlands.

Polymer Performance Materials Group, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, Eindhoven 5600 MB, The Netherlands.

出版信息

ACS Appl Mater Interfaces. 2025 Jun 4;17(22):31685-31697. doi: 10.1021/acsami.5c09198. Epub 2025 May 26.

DOI:10.1021/acsami.5c09198
PMID:40420536
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12147085/
Abstract

Responsive polymers have yet to significantly impact the marketplace. In this Perspective, we offer a glimpse of a possible future industrial-scale responsive polymer. We begin by briefly reviewing two different existing polymer materials, one with high volume, excellent processability, and commercial impact (polyurethanes), the other with stimuli responsive functional properties (liquid crystal elastomers). We explore the possibilities of combining the properties of these two disparate entities into a single material. We offer intriguing possibilities for a bulk polymer with both responsivity and processability that could compete in the market with the long-established residents and discuss some of the research roadblocks that need to be overcome to reach this lofty goal.

摘要

响应性聚合物尚未对市场产生重大影响。在这篇展望文章中,我们简要介绍了一种未来可能实现工业规模生产的响应性聚合物。首先,我们简要回顾两种现有的不同聚合物材料,一种产量高、加工性能优异且具有商业影响力(聚氨酯),另一种具有刺激响应功能特性(液晶弹性体)。我们探讨了将这两种截然不同的聚合物的特性结合到单一材料中的可能性。我们提出了一种兼具响应性和加工性能的块状聚合物的有趣可能性,这种聚合物可以在市场上与长期占据主导地位的产品竞争,并讨论了为实现这一宏伟目标需要克服的一些研究障碍。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/3c82ccbd9ed6/am5c09198_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/c066a5ac5cd1/am5c09198_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/0c947a6850c6/am5c09198_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/9ab930d7204e/am5c09198_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/403bd807846c/am5c09198_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/db15be2dd92b/am5c09198_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/0b1f2e5b624d/am5c09198_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/3c82ccbd9ed6/am5c09198_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/c066a5ac5cd1/am5c09198_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/0c947a6850c6/am5c09198_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/9ab930d7204e/am5c09198_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/403bd807846c/am5c09198_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/db15be2dd92b/am5c09198_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/0b1f2e5b624d/am5c09198_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f69b/12147085/3c82ccbd9ed6/am5c09198_0007.jpg

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本文引用的文献

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Harnessing Imine Chemistry for the Debonding-on-Demand of Polyurethane Adhesives.利用亚胺化学实现聚氨酯胶粘剂的按需脱粘
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Dual-Factor-Controlled Dynamic Precursors Enable On-Demand Thermoset Degradation and Recycling.
双因素控制的动态前驱体实现按需热固性材料降解与回收利用。
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Mechanochromic Displays Based on Photoswitchable Cholesteric Liquid Crystal Elastomers.基于光开关胆甾相液晶弹性体的机械变色显示器
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Sustainable and Scalable Synthesis of Acetal-Containing Polyols as a Platform for Circular Polyurethanes.作为环状聚氨酯平台的含缩醛多元醇的可持续且可扩展合成。
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