A Transfer Learning-Based VGG-16 Model for COD Detection in UV-Vis Spectroscopy.

Chemical oxygen demand (COD) serves as a key indicator of organic pollution in water bodies, and its rapid and accurate detection is crucial for environmental protection. Recently, ultraviolet-visible (UV-Vis) spectroscopy has gained popularity for COD detection due to its convenience and the absence of chemical reagents. Meanwhile, deep learning has emerged as an effective approach for automatically extracting spectral features and predicting COD. This paper proposes transforming one-dimensional spectra into two-dimensional spectrum images and employing convolutional neural networks (CNNs) to extract features and model automatically. However, training such deep learning models requires a vast dataset of water samples, alongside the complex task of labeling this data. To address these challenges, we introduce a transfer learning model based on VGG-16 for spectrum images. In this approach, parameters in the initial layers of the model are frozen, while those in the later layers are fine-tuned with the spectrum images. The effectiveness of this method is demonstrated through experiments conducted on our dataset, where the results indicate that it significantly enhances the accuracy of COD prediction compared to traditional methods and other deep learning methods such as partial least squares regression (PLSR), support vector machine (SVM), artificial neural network (ANN), and CNN-based methods.