[B(OC(CF))] ([FPB])：将这种弱配位阴离子用于固态分子有机金属（SMOM）化学的用途拓展
[B(OC(CF))] ([FPB]): Repurposing This Weakly Coordinating Anion for Solid-State Molecular Organometallic (SMOM) Chemistry.
作者信息
Altus Kristof M, Sajjad M Arif, Macgregor Stuart A, Weller Andrew S
机构信息
Department of Chemistry, University of York, York YO10 5DD, U.K.
EaStCHEM School of Chemistry, North Haugh, University of St. Andrews, St Andrews KY16 9ST, U.K.
出版信息
Organometallics. 2025 May 4;44(10):1018-1021. doi: 10.1021/acs.organomet.5c00112. eCollection 2025 May 26.
The perfluoropinacol borate-based anion [B-(OC(CF))], , is developed as a weakly coordinating anion for single-crystal to single-crystal organometallic solid/gas reactivity, resulting in the isolation and characterization (including periodic DFT and IGMH analysis) of the σ-alkane complex [Rh-(CyPCHCHPCy)-(-ηη-norbornane)]-[FPB]. The synthetically useful solvent-free Na salt, Na-[FPB], and oxonium acid [H-(OEt)]-[FPB] are also reported.
基于全氟频哪醇硼酸酯的阴离子[B-(OC(CF))]，被开发用作一种弱配位阴离子，用于单晶到单晶的有机金属固/气反应，从而分离并表征了σ-烷烃配合物[Rh-(CyPCHCHPCy)-(-ηη-降冰片烷)]-[FPB]（包括周期性密度泛函理论和独立梯度模型 Hirshfeld 分析）。还报道了具有合成实用性的无溶剂钠盐 Na-[FPB]和氧鎓酸[H-(OEt)]-[FPB]。
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