Liu Ruohan, Yu Runnan, Tan Zhan'ao
Beijing Advanced Innovation Center for Soft Matter Science and Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Nanomaterials (Basel). 2025 May 23;15(11):786. doi: 10.3390/nano15110786.
Perovskite solar cells (PSCs) have been regarded as a revolutionary technology in the photovoltaic field, offering a promising pathway for efficient and cost-effective solar energy conversion and demonstrating broad prospects for future green energy technologies. However, critical stability challenges, specifically degradation induced by humidity, light, or heat, severely hinder the commercialization of this technology. Specifically, ultraviolet (UV) radiation in the solar spectrum is a major factor leading to the degradation of perovskite materials. This review focuses on the challenges and strategies for addressing the photostability issues of PSCs. A variety of strategies have been explored, which can be classified as external protection (such as UV-blocking encapsulation technologies) and internal optimization approaches (including precise compositional tuning, the incorporation of functional additives, interface engineering, and improvements to charge transport layers). Finally, this review delves into the key scientific challenges and technological bottlenecks currently faced in addressing the UV stability of PSCs and proposes future directions for solving UV stability issues. It also provides an outlook on the future development prospects of these technologies.
钙钛矿太阳能电池(PSCs)被视为光伏领域的一项革命性技术,为高效且经济高效的太阳能转换提供了一条充满希望的途径,并展示了未来绿色能源技术的广阔前景。然而,关键的稳定性挑战,特别是由湿度、光照或热量引起的降解,严重阻碍了该技术的商业化。具体而言,太阳光谱中的紫外线(UV)辐射是导致钙钛矿材料降解的主要因素。本综述聚焦于解决PSCs光稳定性问题的挑战与策略。人们已经探索了多种策略,这些策略可分为外部保护(如紫外线阻挡封装技术)和内部优化方法(包括精确的成分调整、功能添加剂的掺入、界面工程以及电荷传输层的改进)。最后,本综述深入探讨了目前在解决PSCs紫外线稳定性方面面临的关键科学挑战和技术瓶颈,并提出了解决紫外线稳定性问题的未来方向。它还展望了这些技术的未来发展前景。