Kapuge Dona Nawoda L, Smith Rhett C
Department of Chemistry, Clemson University, Clemson, SC 29634, USA.
Molecules. 2025 Jun 3;30(11):2455. doi: 10.3390/molecules30112455.
Lignin, an abundant and renewable biopolymer, has gained significant attention as a sustainable modifier and building block in polymeric materials. Recent advancements highlight its potential to tailor mechanical, thermal, and barrier properties of polymers while offering a greener alternative to petroleum-based additives. This review provides an updated perspective on the incorporation of lignin into various polymer matrices, focusing on lignin modification techniques, structure-property relationships, and emerging applications. Special emphasis is given to recent innovations in lignin functionalization and its role in developing high-performance, biodegradable, and recyclable materials such as polyurethanes, epoxy resins, phenol-formaldehyde resins, lignin-modified composites, and lignin-based films, coatings, elastomers, and adhesives. These lignin-based materials are gaining attention for potential applications in construction, automated industries, packaging, textiles, wastewater treatment, footwear, supporting goods, automobiles, printing rollers, sealants, and binders.
木质素是一种丰富的可再生生物聚合物,作为聚合物材料中的可持续改性剂和构建单元受到了广泛关注。最近的进展突出了其在调整聚合物的机械、热和阻隔性能方面的潜力,同时为石油基添加剂提供了更环保的替代品。本综述提供了关于将木质素掺入各种聚合物基体的最新观点,重点关注木质素改性技术、结构-性能关系和新兴应用。特别强调了木质素功能化的最新创新及其在开发高性能、可生物降解和可回收材料(如聚氨酯、环氧树脂、酚醛树脂、木质素改性复合材料以及木质素基薄膜、涂层、弹性体和粘合剂)中的作用。这些基于木质素的材料因在建筑、自动化工业、包装、纺织、废水处理、鞋类、支撑用品、汽车、印刷辊、密封剂和粘合剂等潜在应用中受到关注。