用于高效去除纺织和制药废水中污染物的新型生物炭浸渍膜

Innovative Biochar-Infused Membranes for Efficient Pollutant Removal From Textile and Pharmaceutical Wastewater.

作者信息

Gupta Karan, Katiyar Priyanka, Kale Ajay, Khatana Kavita, Yadav Sanjeev

机构信息

Department of Chemical Engineering, Shiv Nadar Institution of Eminence, Gautam Buddh Nagar, Uttar Pradesh, India.

出版信息

Water Environ Res. 2025 Jun;97(6):e70111. doi: 10.1002/wer.70111.

Abstract

In this study, biochar infused polymeric mixed matrix are prepared by spin-coating technique for the adsorption of certain dye and antibiotic pollutants from wastewater samples. This method could potentially be economic in comparison to the classical methods for wastewater treatment. The adsorbent biochar infused in the MMMs is derived from pyrolysis of industrial spice waste (SW) and tannery waste (TW) at 500°C rather than pyrolysis of expensive virgin materials. After the characterization studies (proximate analysis, FESEM, BET, point of zero charge, and XRF) on the biochar and the membrane samples, the adsorption studies are carried out on Congo red (CR), methylene blue (MB) and tartrazine (Tz) dye, and metronidazole (Mz) and clindamycin hydrochloride (CH). It is found that SW biochar does not show any affinity towards antibiotics pollutant whereas TW biochar can adsorb dyes and antibiotics both. Membrane filtration exhibits slightly lower adsorption efficiency compared with batch adsorption using biochars alone; however, it offers faster processing and the advantage of continuous operation. For the optimization study, the initial concentration and pH of the solution were varied between 50-150 mg/L and pH 4-10, respectively. Maximum removal efficiencies of 60%, 83%, 58%, 47%, and 58% were achieved for CR, MB, Tz, Mz, and CH, respectively, at their optimized concentrations and pH conditions. Additionally, regeneration and reusability studies indicate that the membranes can be effectively regenerated by simple washing with distilled water and reused for up to five adsorption cycles. SUMMARY: Biochar infused membranes are produced using spin coater using spice waste and tannery waste. Surface area increases when biochar is infused with polymer to prepare membrane. Spice waste-based membranes show removal of methylene blue and Congo red dyes only. Tannery waste-based membranes can adsorb methylene blue, Congo red, metronidazole, and clindamycin.

摘要

在本研究中,通过旋涂技术制备了生物炭浸渍的聚合物混合基质,用于吸附废水样品中的某些染料和抗生素污染物。与传统的废水处理方法相比,该方法可能具有经济性。浸渍在混合基质膜中的吸附剂生物炭源自工业香料废料(SW)和制革废料(TW)在500°C下的热解,而非昂贵的原始材料的热解。在对生物炭和膜样品进行表征研究(近似分析、场发射扫描电子显微镜、比表面积测定、零电荷点和X射线荧光光谱分析)之后,对刚果红(CR)、亚甲基蓝(MB)和柠檬黄(Tz)染料以及甲硝唑(Mz)和盐酸克林霉素(CH)进行了吸附研究。结果发现,SW生物炭对抗生素污染物没有任何亲和力,而TW生物炭既能吸附染料又能吸附抗生素。与单独使用生物炭的分批吸附相比,膜过滤的吸附效率略低;然而,它提供了更快的处理速度和连续操作的优势。为了进行优化研究,溶液的初始浓度和pH值分别在50 - 150 mg/L和pH 4 - 10之间变化。在优化的浓度和pH条件下,CR、MB、Tz、Mz和CH的最大去除效率分别达到了60%、83%、58%、47%和58%。此外,再生和可重复使用性研究表明,通过用蒸馏水简单洗涤,膜可以有效地再生,并可重复使用多达五个吸附循环。总结:使用旋涂器利用香料废料和制革废料制备了生物炭浸渍膜。当生物炭与聚合物混合制备膜时,表面积增加。基于香料废料的膜仅显示出对亚甲基蓝和刚果红染料的去除。基于制革废料的膜可以吸附亚甲基蓝、刚果红、甲硝唑和克林霉素。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索