Xie Wei, Ma Hao, Cao Chuangguang, Wang Yating, Qiao Yanhui, Teng Junjiang, Li Ning, Yue Chaochao
College of Chemistry, Guangdong University of Petrochemical Technology, Maoming 525000, China.
Materials (Basel). 2025 Jun 16;18(12):2818. doi: 10.3390/ma18122818.
Analcime has demonstrated potential for a variety of applications in technology, especially in adsorption and heterogeneous catalysis. In this study, synthetic analcime was investigated by using sea sand as a silica source. Sea sand was first treated with HNO and NaOH. The pretreated sea sand as the silica resource and Al(NO) as the aluminum source were used for the hydrothermal synthesis of analcime with different ratios of Si/Al and Na/Si. The products obtained under different conditions were characterized by X-ray diffraction. The results showed that analcime synthesized using acid-treated sea sand was mixed with other impurities, such as quartz and sodalite. Pure analcime was obtained using alkali-treated sea sand as the silica source. The analcime prepared under an optimized synthesis condition was further investigated via SEM, FT-IR, and TG. The particle size of the prepared analcime ranged from 40 to 50 μm. The adsorption ability of analcime was studied, and the Cu adsorption process was found to follow a -second-order kinetic model.
方沸石已在多种技术应用中展现出潜力,尤其是在吸附和多相催化方面。在本研究中,以海砂为硅源对合成方沸石进行了研究。海砂首先用硝酸和氢氧化钠处理。将预处理后的海砂作为硅源,硝酸铝作为铝源,用于水热合成不同硅铝比和钠硅比的方沸石。通过X射线衍射对不同条件下获得的产物进行了表征。结果表明,用酸处理过的海砂合成的方沸石与石英和方钠石等其他杂质混合。使用碱处理过的海砂作为硅源获得了纯方沸石。通过扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)和热重分析(TG)对在优化合成条件下制备的方沸石进行了进一步研究。制备的方沸石粒径范围为40至50μm。对方沸石的吸附能力进行了研究,发现铜的吸附过程遵循二级动力学模型。