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熟料和煤渣颗粒级配对混合水泥及相关砂浆性能的影响

Influence of Clinker and Cinder Particle Gradation on the Properties of Blended Cement and Associated Mortars.

作者信息

Shang Runze, Huang Dexiang, Cai Wenju, Niu Longlong, Chen Bi, Zhang Xinyu, Li Wei, Deng Min

机构信息

College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China.

Hefei Cement Research & Design Institute Corp., Ltd., Hefei 230051, China.

出版信息

Materials (Basel). 2025 Jun 17;18(12):2864. doi: 10.3390/ma18122864.

DOI:10.3390/ma18122864
PMID:40572995
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12194932/
Abstract

The high-hydrolysis reactivity cement clinker powder in cement plays a major role in cement's cementation, while low-hydrolysis reactivity mineral admixture powders, such as slag, m mainly serve as a filler. Through optimizing the particle matching of cement clinker powder and slag powder, the mechanical properties of cement can be enhanced. In this study, clinker and slag with differing levels of fineness were obtained by separate grinding, and the particle gradation of clinker powder and slag powder in the cement was optimized. Fine clinker particles were mixed with coarse slag particles to systematically explore their effects on the rheology of cement paste, the formation of hydration products, the evolution of the pore structure, and the material's mechanical properties. Through experimental tests and microscopic analysis, the mechanism whereby particle gradation is regulated by separate grinding was revealed. The findings of the study are as follows: with the same amount of cinder, finer clinker requires a higher water content of standard consistency. The addition of coarse cinder effectively reduces the standard-consistency water requirement of the blended cement. Fine grinding of coal cinder fails to enhance cement strength effectively but markedly raises the standard-consistency water demand. Thus, the specific surface area of coal cinder should be maintained at approximately 210 m/kg.

摘要

水泥中高水解活性的水泥熟料粉在水泥胶结中起主要作用,而低水解活性的矿物掺和料粉,如矿渣粉,主要起填充作用。通过优化水泥熟料粉与矿渣粉的颗粒匹配,可以提高水泥的力学性能。本研究通过分别粉磨得到不同细度的熟料和矿渣,优化了水泥中熟料粉和矿渣粉的颗粒级配。将细熟料颗粒与粗矿渣颗粒混合,系统地探讨了它们对水泥浆体流变学、水化产物形成、孔结构演变及材料力学性能的影响。通过试验测试和微观分析,揭示了分别粉磨调控颗粒级配的机理。研究结果如下:在矿渣用量相同的情况下,熟料越细,标准稠度需水量越高。加入粗矿渣可有效降低复合水泥的标准稠度需水量。细磨矿渣不能有效提高水泥强度,但会显著提高标准稠度需水量。因此,矿渣的比表面积应保持在约210m²/kg。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3294/12194932/0fa155cdb41e/materials-18-02864-g013.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3294/12194932/5b60227874cf/materials-18-02864-g009.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3294/12194932/0fa155cdb41e/materials-18-02864-g013.jpg

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本文引用的文献

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Environmental radiological risk assessment of a coal ash and slag disposal site with the use of the ERICA Tool.利用 ERICA 工具对煤灰渣处置场的环境放射性风险进行评估。
J Environ Radioact. 2019 Nov;208-209:106018. doi: 10.1016/j.jenvrad.2019.106018. Epub 2019 Jul 20.