利用生姜提取物绿色合成氧化锡(SnO)纳米颗粒用于光催化降解废水中的有机染料

Green Synthesis of Tin Oxide (SnO) Nanoparticles Using Ginger Extracts for Photocatalytic Degradation of Organic Dyes in Wastewater.

作者信息

Sivarajan Yuvana, Ishak Khairul Anwar, Yaacob Jamilah Syafawati

机构信息

Institute of Biological Sciences, Faculty of Science, Universiti Malaya, 50603, Kuala Lumpur, Malaysia.

Institute of Systems Biology, Universiti Kebangsaan Malaysia, 43600, UKM Bangi, Selangor, Malaysia.

出版信息

Appl Biochem Biotechnol. 2025 Jun 27. doi: 10.1007/s12010-025-05293-2.

Abstract

One of the main issues that has been receiving great attention globally is the pollution of water resources with dyes, as the chemicals present in them are carcinogenic and harmful to aquatic organisms and humans. Metal oxide nanoparticles synthesized using plant extracts have recently emerged as the best option to address this problem as they provide an eco-friendly and inexpensive approach for a clean water supply. This study describes the photocatalytic degradation of four different types of dyes-methylene blue (MB), rhodamine B (RB), Eriochrome black-T (EB), and methyl orange (MO) using tin oxide nanoparticles (SnO NPs) synthesized with ginger (Zingiber officinale) extract. From the results, the SnO NPs play a remarkable role in degrading all the dyes even though they require a longer time to reach maximum degradation. This study also describes the biosynthetic preparation of SnO NPs, which have a  tetragonal structure, prepared using the optimum parameters of 0.02 g mL of ginger extract, 0.5 M of tin (II) chloride dihydrate (SnCl.HO), and reaction pH of 5. SnO NPs were characterized using powder X-ray diffraction (XRD) to evaluate their crystallinity and composition, Fourier transform infrared (FTIR) to identify the changes in functional groups of SnO NPs, and ultraviolet-visible (UV-Vis) spectroscopy to analyze the optical properties of SnO NPs through band gap calculation. The photocatalytic activity of SnO NPs was then studied through their efficiency in degrading the four dyes. A toxicity test was also carried out in this study using brine shrimp (Artemia salina) to ensure the safety of the synthesized SnO NPs made with ginger extract for use in aquatic environments to degrade pollutants. The positive results obtained indicate their potential as a good photocatalyst for water remediation.

摘要

全球范围内备受关注的主要问题之一是染料对水资源的污染,因为其中所含的化学物质具有致癌性,对水生生物和人类有害。最近,利用植物提取物合成的金属氧化物纳米颗粒成为解决这一问题的最佳选择,因为它们为清洁供水提供了一种环保且廉价的方法。本研究描述了用姜(姜科植物姜)提取物合成的氧化锡纳米颗粒(SnO NPs)对四种不同类型染料——亚甲基蓝(MB)、罗丹明B(RB)、铬黑T(EB)和甲基橙(MO)的光催化降解。结果表明,SnO NPs在降解所有染料方面发挥了显著作用,尽管它们需要更长时间才能达到最大降解程度。本研究还描述了SnO NPs的生物合成制备方法,其具有四方结构,制备时使用的最佳参数为0.02 g/mL的姜提取物、0.5 M的二水合氯化亚锡(SnCl₂·H₂O)以及反应pH值为5。使用粉末X射线衍射(XRD)对SnO NPs进行表征以评估其结晶度和组成,使用傅里叶变换红外光谱(FTIR)来识别SnO NPs官能团的变化,并通过紫外可见(UV-Vis)光谱通过带隙计算分析SnO NPs的光学性质。然后通过SnO NPs降解四种染料的效率研究其光催化活性。本研究还使用卤虫(卤虫)进行了毒性测试,以确保用姜提取物合成的SnO NPs在用于降解水生环境中的污染物时的安全性。所获得的阳性结果表明它们作为水修复良好光催化剂的潜力。

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