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通过对AgNbO纳米颗粒进行表面改性来增强环氧树脂复合材料的介电特性和直流闪络性能。

Enhancing the dielectric characteristics and DC flashover of epoxy resin composites by surface modification of AgNbO nano particles.

作者信息

Khan Muhammad Zeeshan, Aslam Farooq, Alsaif Faisal

机构信息

German Institute of Engineering, Chongqing College of Mobile Communication, Chongqing, 401520, Hechuan, People's Republic of China.

Department of Electrical and Electronics Engineering, Changzhou Institute of Technology, Changzhou, 213032, Jiangsu, People's Republic of China.

出版信息

Sci Rep. 2025 Jul 2;15(1):23522. doi: 10.1038/s41598-025-09151-3.

Abstract

The advancement of industrial technology has led to power modules facing challenges such as elevated temperatures, high voltages, and increased frequencies. The conventional epoxy resin (Ep) fails to satisfy the demands of high voltage and superior insulation. This study involved the synthesis of Ep resin/ AgNbO nanocomposites aimed at addressing insulating flaws. AgNbO was modified using the silane coupling agent KH550. The changes in the molecular chain after incorporating of unmodified and modified AgNbO were evaluated through FTIR analysis. The SEM results indicate that following modification, AgNbO particles are evenly distributed within the Ep resin matrix, demonstrating a lack of agglomeration. From thermal conductivity result it was found that modification of AgNbO shows an enhancement of thermal conductivity, attributed to the reduction of interfacial phonon scattering and thermal resistance within the Ep resin. Additionally, the dielectric constant and dielectric loss in composites are greatly impacted by the addition of AgNbO. According to the DC breakdown strength result, the addition of modified AgNbO enhanced the process and caused deeper traps to form inside the bulk matrix. The distribution of trap energy levels is determined by Thermal Stimulated Depolarization Current (TSDC), which indicates that the incorporation of AgNbO results in an increase in trap energy levels. Furthermore, the incorporation of 1 wt% AgNbO particle into Ep resin has been observed to enhance the energy level of deep traps. After AgNbO was added, DC Flashover in both air and vacuum significantly increased in comparison to pure Ep resin.

摘要

工业技术的进步使功率模块面临诸如温度升高、电压高和频率增加等挑战。传统的环氧树脂(Ep)无法满足高电压和卓越绝缘的要求。本研究涉及Ep树脂/AgNbO纳米复合材料的合成,旨在解决绝缘缺陷问题。使用硅烷偶联剂KH550对AgNbO进行改性。通过傅里叶变换红外光谱(FTIR)分析评估了未改性和改性AgNbO掺入后分子链的变化。扫描电子显微镜(SEM)结果表明,改性后AgNbO颗粒均匀分布在Ep树脂基体中,未出现团聚现象。从热导率结果发现,AgNbO的改性显示出热导率的提高,这归因于Ep树脂内界面声子散射和热阻的降低。此外,复合材料中的介电常数和介电损耗受AgNbO添加量的极大影响。根据直流击穿强度结果,添加改性AgNbO增强了该过程,并导致在块状基体内部形成更深的陷阱。通过热刺激去极化电流(TSDC)确定陷阱能级的分布,这表明AgNbO的掺入导致陷阱能级增加。此外,已观察到向Ep树脂中掺入1 wt%的AgNbO颗粒可提高深陷阱的能级。添加AgNbO后,与纯Ep树脂相比,在空气和真空中的直流闪络均显著增加。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83b1/12223253/313390fcfa20/41598_2025_9151_Fig1_HTML.jpg

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