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量化城市甲烷排放:五个城市区域单点测量的效用

Scaling Urban Methane Emissions: Utility of Single-Site Measurements in Five Urban Domains.

作者信息

Mueller Kimberly L, Karion Anna, Lopez-Coto Israel, Marrs Julia, Yadav Vineet, Plant Genevieve, Pitt Joseph, Barkley Zachary R, Whetstone James

机构信息

Special Programs Office, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, United States.

Jet Propulsion Laboratory, Pasadena, California 91109, United States.

出版信息

Environ Sci Technol. 2025 Jul 22;59(28):14399-14409. doi: 10.1021/acs.est.5c03844. Epub 2025 Jul 9.

DOI:10.1021/acs.est.5c03844
PMID:40633562
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12288071/
Abstract

Urban methane (CH) missions remain poorly understood due to limited observational constraints. Most estimates rely on bottom-up inventories based on assumed emission factors and activity data or downscaling methods, which often underestimate emissions, sometimes by a factor of 2 or more in United States and European cities. While satellite and mobile observations can improve understanding, they face limitations in spatial resolution, coverage, and frequency. In contrast, fixed in situ measurements calibrated to World Meteorological Organization standards offer high precision continuous data, although with limited spatial coverage due to logistical constraints. This study uses in situ observations from single tower sites in five northeastern United States cities to estimate total urban CH emissions using a Bayesian scaling factor framework. Despite limited spatial sampling, the approach yields robust emission estimates consistent with other studies. To explore drivers of variability, the analysis examines correlations between inferred emissions and urban characteristics including population, residential gas usage, and infrastructure. Results show that residential building volume outperforms population as a predictor in some regions, highlighting the importance of infrastructure-specific factors. By demonstrating a scalable observation-based approach using minimal sites, this work addresses key gaps in urban CH monitoring and emphasizes the value of robust measurements and tailored proxies for improving emission estimates in diverse urban settings.

摘要

由于观测限制有限,城市甲烷(CH)排放仍知之甚少。大多数估算依赖于基于假定排放因子和活动数据的自下而上清单或降尺度方法,这些方法往往低估排放量,在美国和欧洲城市,有时低估幅度达2倍或更多。虽然卫星和移动观测可以增进了解,但它们在空间分辨率、覆盖范围和频率方面存在局限性。相比之下,按照世界气象组织标准校准的固定原位测量可提供高精度连续数据,不过由于后勤限制,空间覆盖范围有限。本研究利用美国东北部五个城市单塔站点的原位观测数据,采用贝叶斯比例因子框架估算城市CH总排放量。尽管空间采样有限,但该方法得出的排放估算结果与其他研究一致且可靠。为了探究变率驱动因素,分析考察了推断排放量与包括人口、住宅燃气使用量和基础设施在内的城市特征之间的相关性。结果表明,在某些地区,住宅建筑体量作为预测指标比人口更有效,凸显了特定基础设施因素的重要性。通过展示一种使用最少站点的可扩展的基于观测的方法,这项工作填补了城市CH监测的关键空白,并强调了可靠测量和量身定制的代理变量对于改善不同城市环境中排放估算的价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/a05b34f0258e/es5c03844_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/696c305f30a9/es5c03844_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/cf6063d88064/es5c03844_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/0b5bfb4646eb/es5c03844_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/d0d20395bea0/es5c03844_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/a05b34f0258e/es5c03844_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/696c305f30a9/es5c03844_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/cf6063d88064/es5c03844_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/0b5bfb4646eb/es5c03844_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/d0d20395bea0/es5c03844_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7b1/12288071/a05b34f0258e/es5c03844_0005.jpg

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本文引用的文献

1
Site selection and effects of background towers on urban CO estimates: A case study from central downtown Zhengzhou in China.站点选择与背景塔对城市 CO 估算的影响:以中国郑州市中心城区为例。
Environ Res. 2024 Dec 15;263(Pt 2):120169. doi: 10.1016/j.envres.2024.120169. Epub 2024 Oct 16.
2
Underestimation of Thermogenic Methane Emissions in New York City.低估了纽约市的产热甲烷排放。
Environ Sci Technol. 2024 May 28;58(21):9147-9157. doi: 10.1021/acs.est.3c10307. Epub 2024 May 14.
3
Ground-Based Mobile Measurements to Track Urban Methane Emissions from Natural Gas in 12 Cities across Eight Countries.
基于地面的移动测量,以追踪八国12个城市天然气产生的城市甲烷排放。
Environ Sci Technol. 2024 Feb 6;58(5):2271-2281. doi: 10.1021/acs.est.3c03160. Epub 2024 Jan 25.
4
Methane Emissions Show Recent Decline but Strong Seasonality in Two US Northeastern Cities.甲烷排放显示美国两个东北部城市近期呈下降趋势,但季节性很强。
Environ Sci Technol. 2023 Dec 5;57(48):19565-19574. doi: 10.1021/acs.est.3c05050. Epub 2023 Nov 9.
5
A Gridded Inventory of Annual 2012-2018 U.S. Anthropogenic Methane Emissions.网格化的 2012-2018 年美国人为源甲烷排放清单。
Environ Sci Technol. 2023 Oct 31;57(43):16276-16288. doi: 10.1021/acs.est.3c05138. Epub 2023 Oct 19.
6
Single-blind validation of space-based point-source detection and quantification of onshore methane emissions.基于天基的点源探测和量化陆上甲烷排放的单盲验证。
Sci Rep. 2023 Mar 7;13(1):3836. doi: 10.1038/s41598-023-30761-2.
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Background conditions for an urban greenhouse gas network in the Washington, D.C. and Baltimore metropolitan region.华盛顿特区和巴尔的摩大都市区城市温室气体网络的背景条件。
Atmos Chem Phys. 2021;21(8). doi: 10.5194/acp-21-6257-2021.
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Majority of US urban natural gas emissions unaccounted for in inventories.美国城市天然气排放量大部分未被列入清单。
Proc Natl Acad Sci U S A. 2021 Nov 2;118(44). doi: 10.1073/pnas.2105804118.
9
The Impact of COVID-19 on CO Emissions in the Los Angeles and Washington DC/Baltimore Metropolitan Areas.新冠疫情对洛杉矶及华盛顿特区/巴尔的摩都会区一氧化碳排放的影响
Geophys Res Lett. 2021 Jun 16;48(11):e2021GL092744. doi: 10.1029/2021GL092744. Epub 2021 Jun 7.
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Earth Syst Sci Data. 2020;12(1). doi: https://doi.org/10.5194/essd-12-699-2020.