Xu Zhenli, Liu Jing, Kreissl Johanna, Oellig Claudia, Vetter Walter, Steinhaus Martin, Frank Stephanie
Leibniz Institute for Food Systems Biology at the Technical University of Munich (Leibniz-LSB@TUM), Lise-Meitner-Straße 34, 85354 Freising, Germany.
Institute of Food Chemistry, University of Hohenheim, Garbenstraße 28, 70599 Stuttgart, Germany.
Foods. 2025 Jun 28;14(13):2303. doi: 10.3390/foods14132303.
is a culinary herb from Asia. Its edible rhizomes and leaves have a fishy aroma, the molecular background of which was unknown. A comparative aroma extract dilution analysis applied to fresh rhizomes and leaves resulted in 44 and 41 odorants, respectively, 38 of which were present with FD factors ≥1 in both samples. The odorant with the highest FD factors, whether in the rhizomes or leaves, was identified as metallic, soapy, fishy smelling 3-oxododecanal. Toward clarifying its tautomeric composition, quantum calculations suggested a predominance of the enol forms in the plant. However, the form perceived at the sniffing port during GC-O remained unclear.
是一种来自亚洲的烹饪香草。其可食用的根茎和叶子有鱼腥味,其分子背景尚不清楚。对新鲜根茎和叶子进行的比较香气提取物稀释分析分别得到了44种和41种气味物质,其中38种在两个样品中的风味稀释(FD)因子均≥1。无论是在根茎还是叶子中,FD因子最高的气味物质被鉴定为具有金属味、肥皂味、鱼腥味的3-氧代十二醛。为了阐明其互变异构体组成,量子计算表明该植物中烯醇形式占主导。然而,在气相色谱-嗅觉测定(GC-O)过程中在嗅闻口所感知到的形式仍不清楚。