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用于高性能对称超级电容器器件应用的可持续甘蔗渣衍生活性炭

Sustainable Sugarcane Bagasse-Derived Activated Carbon for High-Performance Symmetric Supercapacitor Devices Applications.

作者信息

Rajivgandhi Perumal, Thirumal Vediyappan, Sekar Alagan, Kim Jinho

机构信息

Department of Chemistry, Nehru Memorial College, Bharathidasan University, Puthanampatti, Trichy 621 007, Tamilnadu, India.

Department of Mechanical Engineering, Yeungnam University, Gyeongsan-si 38541, Gyeongbuk-do, Republic of Korea.

出版信息

Nanomaterials (Basel). 2025 Jul 2;15(13):1028. doi: 10.3390/nano15131028.

Abstract

In this study, sugarcane bagasse (SCB), an abundant agricultural byproduct, was transformed into activated carbon via a controlled thermochemical pyrolysis route for high-performance energy storage applications. Herein, we utilized the activated carbon derived from pure sugarcane bagasse (SCB-AC) and further activated using KOH (SCB-KOH-AC) as an electrode material in aqueous symmetric supercapacitor configurations. The synthesized activated carbon was subjected to analysis using a range of characteristics including FT-Raman spectroscopy, which was employed to confirm the functional groups present in the carbon materials. The XPS analysis provided insights into the elemental composition and ionic states. The SEM analysis revealed that both activated carbon and KOH/activated carbon materials exhibited a layered or stacked, albeit slightly random, orientation. Electrochemical studies demonstrated that the synthesized carbon electrodes exhibited impressive specific capacitance values of (SCB) activated carbon (132.20 F/g) and KOH-activated, pure SCB AC (SCB-A) 253.41 F/g at 0.5 A/g. Furthermore, the SCB KOH-activated carbon (AC) electrode revealed a higher specific capacitance value and A//SCB-A symmetric devices delivered energy density reaching 17.91 Wh/kg and power density up to 2990 W/kg. The KOH-activated carbon electrode demonstrated remarkable cycling stability retaining 93.89%, even after 10,000 cycles. These results suggest that the sugarcane bagasse-derived activated carbon is a sustainable and low-cost candidate for next-generation supercapacitor electrodes. The results demonstrate enhanced capacitance, stability, and pore structure tailored for energy storage applications. The KOH-activated carbon SCB carbon symmetric device with symmetric electrodes exhibited a suitable bio-mass carbon for future energy storage applications.

摘要

在本研究中,甘蔗渣(SCB)作为一种丰富的农业副产品,通过可控的热化学热解路线转化为活性炭,用于高性能储能应用。在此,我们将纯甘蔗渣衍生的活性炭(SCB-AC)并进一步用KOH活化(SCB-KOH-AC)用作水系对称超级电容器配置中的电极材料。对合成的活性炭进行了一系列特性分析,包括FT-拉曼光谱,用于确认碳材料中存在的官能团。XPS分析提供了有关元素组成和离子状态的信息。SEM分析表明,活性炭和KOH/活性炭材料均呈现出层状或堆叠状,尽管略有随机取向。电化学研究表明,合成的碳电极在0.5 A/g时表现出令人印象深刻的比电容值,(SCB)活性炭为132.20 F/g,KOH活化的纯SCB AC(SCB-A)为253.41 F/g。此外,SCB KOH活化碳(AC)电极显示出更高的比电容值,A//SCB-A对称器件的能量密度达到17.91 Wh/kg,功率密度高达2990 W/kg。KOH活化碳电极表现出卓越的循环稳定性,即使在10000次循环后仍保留93.89%。这些结果表明,甘蔗渣衍生的活性炭是下一代超级电容器电极的可持续且低成本候选材料。结果表明,其电容、稳定性和孔隙结构得到增强,适合储能应用。具有对称电极的KOH活化碳SCB碳对称器件展示了一种适用于未来储能应用的生物质碳。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/633a/12251455/a298b4b2aa6d/nanomaterials-15-01028-g001.jpg

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