Song Guozhen, Tian Yijun, Wang Jieni, Zhang Shuqin, Hou Haodong, Wei Chenlin, Cao Leichang, Zhang Jinglai, Zhang Shicheng
Henan Key Laboratory of Protection and Safety Energy Storage for Light Metal Materials, College of Chemistry and Molecular Sciences, Henan University Kaifeng 475004 China
Miami College, Henan University Kaifeng 475004 China.
RSC Adv. 2025 Jun 18;15(26):20657-20667. doi: 10.1039/d5ra00450k. eCollection 2025 Jun 16.
This study presents a method for the synthesis of nitrogen-doped porous carbon (NAPC) from nitrogen-rich superabsorbent material (SAP) found in waste baby diapers for application as an electrode material for high-performance supercapacitors. Through rapid pyrolysis and KOH activation, the resulting NAPC material exhibited a high specific surface area and abundant microporous structure, which promoted efficient ion transport and energy storage. Electrochemical testing demonstrated that the NAPC-650-4 sample achieved a specific capacitance of 353 F g at a current density of 1 A g in a 6 M KOH electrolyte, with a capacitance retention rate of 87.65% after 10 000 cycles. This finding indicates the material's excellent rate capability and cycle stability. Furthermore, the symmetric supercapacitor assembled from NAPC-650-4 delivered an energy density of 7.22 Wh kg at a power density of 125 W kg, which showed its potential for high-power applications. This research not only provides a feasible green solution for recycling waste diapers but also a new approach for the development of high-performance electrode materials.
本研究提出了一种从废弃婴儿尿布中富含氮的高吸水性材料(SAP)合成氮掺杂多孔碳(NAPC)的方法,用于作为高性能超级电容器的电极材料。通过快速热解和KOH活化,所得的NAPC材料表现出高比表面积和丰富的微孔结构,这促进了高效的离子传输和能量存储。电化学测试表明,在6 M KOH电解液中,NAPC-650-4样品在1 A g的电流密度下实现了353 F g的比电容,在10000次循环后电容保持率为87.65%。这一发现表明该材料具有优异的倍率性能和循环稳定性。此外,由NAPC-650-4组装的对称超级电容器在125 W kg的功率密度下提供了7.22 Wh kg的能量密度,这显示了其在高功率应用方面的潜力。本研究不仅为回收废弃尿布提供了一种可行的绿色解决方案,也为开发高性能电极材料提供了一种新方法。