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基于环保型烷基链桥接木质素的聚合物高度分散的碳纳米管及其性能

Carbon Nanotube Highly Dispersed by Eco-Friendly Alkyl Chain-Bridged Lignin-Based Polymer and Its Properties.

作者信息

Hong Nanlong, Huang Jinrong, Li Quanyou, Chen Yanjun, Chen Qingui

机构信息

School of Chemical Engineering and Energy Technology, Dongguan University of Technology, Dongguan 523808, China.

出版信息

ACS Omega. 2025 Jul 7;10(27):28811-28820. doi: 10.1021/acsomega.4c10980. eCollection 2025 Jul 15.

Abstract

In this study, carbon nanotube (CNT) suspensions were highly dispersed using an alkyl chain-bridged lignin polymer. UV-vis and Fourier transform infrared spectroscopy (FTIR) were applied to characterize the structure of functionalized CNT products. The result demonstrates that functionalized CNTs have been successfully prepared. The photo, particle size distribution analysis, and SEM imaging showed that the dispersion efficiency of CNT suspension was significantly improved. Cyclic voltammetry (CV) was used to test the oxidation-reduction properties of CNT products. The results showed that all CNTs exhibit an obvious redox peak, and the oxidation potential decreases slightly with the increase of lignin polymer dosage. The results of conductivity and impedance also showed that the 1% ASL can effectively reduce electrochemical impedance and significantly enhance the electrochemical performance of CNTs. TG was used to investigate the thermal stability of the CNT products. The results showed that the stability of functionalized CNTs is relatively excellent, with a residual mass of up to 97% at 250 °C. Moreover, the degree of defect and disorder was reduced after doping with lignin-based polymer. It has been successful in addressing the limitations of CNTs and facilitating their application. Above all, the results show that CNT suspension can be highly dispersed by eco-friendly lignin-based polymer, which will facilitate its application as an electrode material and widen the potential applications of lignin.

摘要

在本研究中,使用烷基链桥接木质素聚合物对碳纳米管(CNT)悬浮液进行了高度分散。采用紫外可见光谱和傅里叶变换红外光谱(FTIR)对功能化碳纳米管产物的结构进行了表征。结果表明,已成功制备出功能化碳纳米管。照片、粒度分布分析和扫描电子显微镜成像表明,碳纳米管悬浮液的分散效率显著提高。采用循环伏安法(CV)测试了碳纳米管产物的氧化还原性能。结果表明,所有碳纳米管均呈现出明显的氧化还原峰,且氧化电位随木质素聚合物用量的增加略有降低。电导率和阻抗结果还表明,1%的ASL能有效降低电化学阻抗,并显著提高碳纳米管的电化学性能。采用热重分析法(TG)研究了碳纳米管产物的热稳定性。结果表明,功能化碳纳米管的稳定性相对优异,在250℃时残余质量高达97%。此外,用木质素基聚合物掺杂后,缺陷和无序程度降低。它成功地解决了碳纳米管的局限性并促进了其应用。最重要的是,结果表明,碳纳米管悬浮液可以通过环保的木质素基聚合物实现高度分散,这将有利于其作为电极材料的应用,并拓宽木质素的潜在应用范围。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a94/12268438/2a44400b530a/ao4c10980_0001.jpg

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