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含稀土CeO的紫外光固化涂料的制备与性能

Preparation and properties of a UV-curable coating containing rare earth CeO.

作者信息

Sun Yihua, Li Guoyao, Zhong Rong

机构信息

Department of Materials and Chemistry, School of Environmental & Chemical Engineering, Nanchang Hangkong University Nanchang 330063 China

出版信息

RSC Adv. 2025 Jul 23;15(32):26266-26275. doi: 10.1039/d5ra02778k. eCollection 2025 Jul 21.

Abstract

A UV-curable coating with UV and blue light protection was prepared by incorporating modified rare earth nano cerium dioxide (CeO) treated with the silane coupling agent KH570. The structures of the modified CeO and the resulting UV-curable coating were characterized using Fourier Transform Infrared Spectroscopy, X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis. UV spectral analysis was conducted to evaluate the UV shielding performance of the coating. The results demonstrated that the nano-CeO was uniformly distributed within the polymer matrix of the cured coating. The coating exhibited UV shielding capabilities ranging from 58% to 98% in the UVB region (280-315 nm), as well as effective protection against blue light (400-450 nm), and the visible light transmittance is maintained at about 90%. The UV-cured coating also displayed excellent mechanical properties, indicating its potential application in electronic products.

摘要

通过掺入经硅烷偶联剂KH570处理的改性稀土纳米二氧化铈(CeO)制备了一种具有紫外线和蓝光防护功能的紫外光固化涂料。使用傅里叶变换红外光谱、X射线衍射、扫描电子显微镜和热重分析对改性CeO和所得紫外光固化涂料的结构进行了表征。进行了紫外光谱分析以评估涂料的紫外线屏蔽性能。结果表明,纳米CeO均匀分布在固化涂料的聚合物基质中。该涂料在UVB区域(280 - 315 nm)的紫外线屏蔽能力为58%至98%,同时对蓝光(400 - 450 nm)具有有效防护,可见光透过率保持在约90%。该紫外光固化涂料还表现出优异的机械性能,表明其在电子产品中的潜在应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e23d/12284964/901a908b6d92/d5ra02778k-s1.jpg

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